首页> 外国专利> Initiated scale-free formation of vinyl chloride polymers using washing liquid at temperature affecting initiator half-life

Initiated scale-free formation of vinyl chloride polymers using washing liquid at temperature affecting initiator half-life

机译:在影响引发剂半衰期的温度下使用洗涤液引发的无鳞氯乙烯聚合物的引发

摘要

A method for preparing vinyl chloride polymers which comprises polymerizing vinyl chloride monomer or a vinylic monomer mixture mainly composed of vinyl chloride in an aqueous medium in the presence of a polymerization initiator, characterized by washing a piping and an opening of a polymerizer, for charging the polymerization initiator into the polymerizer, with water, steam or a washing liquid capable of lowering the half-life of the polymerization initiator to not more than 30 minutes after introducing the initiator into the polymerizer. The method makes it possible to eliminate the formation of polymer scales on the piping and the opening for charging the polymerization initiator into a polymerizer and, therefore, the yield of the vinyl chloride polymers can greatly improved and the production cost can be substantially saved. Moreover, the polymer product does not include any materials used for washing said portions and thus polymer product of high quality can be provided in a high yield.
机译:一种制备氯乙烯聚合物的方法,该方法包括在聚合引发剂的存在下,在水性介质中聚合氯乙烯单体或主要由氯乙烯组成的乙烯基单体混合物,其特征在于,清洗配管和打开聚合器的开口,以填充聚氯乙烯。在将引发剂引入聚合反应器中之后,用水,蒸汽或能够将聚合引发剂的半衰期降低至不超过30分钟的洗涤液将其加入聚合反应器中。该方法使得可以消除在管道上和用于将聚合引发剂装入聚合器中的开口上的聚合物水垢的形成,因此,可以大大提高氯乙烯聚合物的产率,并且可以基本上节省生产成本。而且,该聚合物产品不包括用于洗涤所述部分的任何材料,因此可以高产量提供高质量的聚合物产品。

著录项

  • 公开/公告号US5100988A

    专利类型

  • 公开/公告日1992-03-31

    原文格式PDF

  • 申请/专利权人 SHIN-ETSU CHEMICAL CO. LTD.;

    申请/专利号US19900494325

  • 发明设计人 SHIGEHIRO HOSHIDA;TADASHI AMANO;

    申请日1990-03-16

  • 分类号C08F14/06;

  • 国家 US

  • 入库时间 2022-08-22 05:23:07

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