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Heat-cured powder adhesive for high-strength composites - has homogeneous mixt. of solid and liq. epoxy resins, PVAC plastomer, hardener and/or fillers

机译:用于高强度复合材料的热固化粉末胶粘剂-具有均匀的混合物。固体和液体。环氧树脂],PVAC塑性体,硬化剂和/或填料

摘要

One-component solvent-free, heat-curing, epoxide/ plastomer-based powder adhesive (I) for high-strength composites consists of a homogeneous mixt. of solid and liq. epoxy esins with PVAc plastomer and hardener, and possibly other additives such as elastomers, accelerators, and/or fillers. (I) is produced by mixing the resin mixt. and the PVAc in a kneader, opt. with heating, esp. at 150-180 deg.C, allowing to cool and granulating at room temp. or with cooling, incorporating the hardener (and opt. accelerator), and processing the mixt. at room temp. or below to a free-flowing powder, pref. in a turbo-mill. (I) contains 15-50 (esp. 20-40) wt.% liq. epoxy resin, 10-40 (esp. 15-35) wt.% solid epoxy resin, 10-45 (esp. 15-35) wt.% PVAc, 2.5-10 (esp. 4-8) wt.% hardener, 0-15 (esp. 1-2) wt.% accelerator and 0-90 (esp. 1.5-4.5) wt.% filler; (I) contains nitrile rubber as elastomer, dicyandiamide as hardener and mineral additives as filler; pref. (I) contains 6.0 pts.wt. liq. epoxy resin, 6.2 pts.wt. solid epoxy resin, 5.0 pts.wt. PVAc, 1.0 pt. wt. hardener, 1.0 pt.wt. elastomer, 0.3 pt.wt. accelerator and 0.5 pt.wt. filler. USE/ADVANTAGE - (I) Is useful for bonding friction linings with steel, esp. in brake and clutch linings for vehicles (claimed). The invention provides a homogeneous, 1-component adhesive which meets the demanding requirements for this application (high bond strength, high temp. stability, etc.) (contrast prior-art solvent-free powder adhesives).
机译:高强度复合材料的单组分,无溶剂,热固化,环氧化物/塑性体基粉末粘合剂(I)由均质混合物组成。固体和液体。具有PVAc塑性体和硬化剂的环氧树脂,以及其他可能的添加剂,例如弹性体,促进剂和/或填料。 (I)是通过混合树脂混合物而产生的。选择和捏合机中的PVAc。带加热,特别是在150-180℃下冷却,并在室温下制粒。或冷却后,加入硬化剂(和加速剂),并加工混合物。在室温下或以下为自由流动的粉末,优选。在涡轮磨坊里(I)包含15-50(尤其是20-40)重量%的液体。环氧树脂,10-40(esp。15-35)wt。%固体环氧树脂,10-45(esp。15-35)wt。%PVAc,2.5-10(esp。4-8)wt。%固化剂, 0-15(esp。1-2)wt。%促进剂和0-90(esp。1.5-4.5)wt。%填料; (I)包含丁腈橡胶作为弹性体,双氰胺作为硬化剂和矿物添加剂作为填充剂;偏好(I)包含6.0pts.wt。液体环氧树脂,6.2 pts.wt.固体环氧树脂,5.0pts.wt。 PVAc,1.0磅重量硬化剂,1.0 pt.wt.弹性体,0.3 pt.wt.促进剂和0.5 pt.wt.填料。使用/优点-(I)特别适用于将摩擦衬片与钢粘合。用于车辆的刹车和离合器衬片(已声明)。本发明提供了一种均一的,一种组分的粘合剂,其满足该应用的要求(高粘合强度,高温稳定性等)(对比现有技术的无溶剂粉末粘合剂)。

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