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foerfarande foer framstaellning av vattenabsorberande harzer.

机译:吸水性树脂的生产程序。

摘要

The invention concerns a process for producing water-insoluble water-absorbing resins, which comprises the steps of initiating polymerization of an aquaous solution containing 30 to 80 % by weight of (a) a hydrophilic vinyl monomer having a functional group and (b) a crosslinking agent by supplying the aquaous solution together with (c) a polymerization initiator to a polymerizing apparatus capable of heating and/or cooling surfaces in contact with the aquaous solution, subsequently causing constant temperature polymerization of the solution without agitating the same by controlling the temperature of the system being polymerized to 20 to 70 C, and elevating, if necessary, the temperature of the system to be in excess of 70 ° C in a stage with a polymerization percentage of 70 % or above before completion of polymerization. Obtainable water-insoluble water-absorbing resins have excellent water-absorbing property and have less water-soluble components. Thus, the water-absorbing resins according to the invention are useful for physiological commodities, paper diapers or like sanitary materials, drip absorbing materials, cold water retainers, dew condensation prevention materials for construction materials and so forth.
机译:本发明涉及一种制备水不溶性吸水树脂的方法,该方法包括以下步骤:引发含有30至80重量%的(a)具有官能团的亲水性乙烯基单体和(b)a的水溶液的聚合。通过将水溶液与(c)聚合引发剂一起提供给能够加热和/或冷却与水溶液接触的表面的聚合装置中的交联剂,随后引起溶液的恒温聚合而无需通过控制温度对其进行搅拌将体系的聚合温度升高至20-70℃,并且在聚合完成之前,如果有必要,在聚合百分比为70%或更高的阶段中,将体系的温度升高至超过70℃。可获得的水不溶性吸水树脂具有优异的吸水性能并且具有较少的水溶性组分。因此,根据本发明的吸水树脂可用于生理用品,纸尿布或类似的卫生材料,滴水吸收材料,冷水保持器,建筑材料的防结露材料等。

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