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Improvements to Malcolm Finlayson Clay composition

机译:对Malcolm Finlayson粘土成分的改进

摘要

An organophilic clay gellant useful for gelling organic liquids is disclosed which comprises the reaction product of (a) a smectite-type clay having a cation exchange capacity of at least 75 milliequivalents per 100 grams of said clay; (b) a primary anion selected from the group consisting of anions derived from organic sulfonic acids, alkylsulfates and mixtures thereof containing at least one lineal or branched alkyl group having greater than 9 carbon atoms, aromatic sulfonic acids and mixtures thereof; (c) a secondary anion different from said primary anion and selected from the group consisting of anions derived from organic acids having a pKa of less than about 11.0 and mixtures thereof; and (d) an organic cation is an amount sufficient to satisfy the cation in exchange capacity of said clay and the cationic activity of the primary and secondary anions wherein the resulting organic cation-organic anion complexes are intercalated with the smectite-type clay and wherein the combination of said primary and secondary anion synergistically increases the ease of dispersion of said organophilic clay gellant in an organic liquid.
机译:公开了一种可用于胶凝有机液体的亲有机粘土胶凝剂,它包括:(a)蒙脱石型粘土的反应产物,其每100克所述粘土的阳离子交换容量为至少75毫当量; (b)选自由有机磺酸,烷基硫酸盐及其混合物组成的组中的伯阴离子,其包含至少一个碳原子数大于9的直链或支链烷基,芳族磺酸及其混合物; (c)不同于所述一级阴离子的二级阴离子,其选自由pKa小于约11.0的有机酸衍生的阴离子及其混合物; (d)有机阳离子的量要足以满足阳离子在所述粘土中的交换能力以及伯和仲阴离子的阳离子活性,其中所得的有机阳离子-有机阴离子络合物被蒙脱石型粘土插入,并且其中所述第一和第二阴离子的组合协同增加了所述亲有机性粘土胶凝剂在有机液体中的分散容易性。

著录项

  • 公开/公告号MX160755A

    专利类型

  • 公开/公告日1990-05-09

    原文格式PDF

  • 申请/专利权人 NL CHEMICALS INC.;

    申请/专利号MX19820191874

  • 发明设计人 WILBUR S. MARDIS;CLAUDE MALCOLM FINLAYSON;

    申请日1982-03-18

  • 分类号B01J13/00;

  • 国家 MX

  • 入库时间 2022-08-22 06:18:31

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