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NOVEL TETRATHIAFULVALENE DERIVATIVE AND ELECTROCONDUCTIVE CHARGE TRANSFER COMPLEX USING THE SAME DERIVATIVE
NOVEL TETRATHIAFULVALENE DERIVATIVE AND ELECTROCONDUCTIVE CHARGE TRANSFER COMPLEX USING THE SAME DERIVATIVE
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机译：使用同一衍生物的新型四硫杂富勒烯衍生物和电电荷转移复合物
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摘要
NEW MATERIAL:A tetrathiafulvalene derivative wherein at least one carboxyl group of a compound shown by formula l (R1 to R4 are H or carboxyl but not H at the same time) is formed into N-hydrocarbon group substituted ammonium salt). EXAMPLE:Tetrathiafulvalnoe-2,3,6,7-tetracarboxylic acid di(tetra-n- butylammonium) salt. USE:An electroconductive charge transfer complex obtainable by direct method by simple operation in a short time required, useful as an electron donor providing charge transfer complex having high electroconductivity even in a powder state and supplying a complex by reaction with an electron acceptor, preferably usable as electroconductive material of electronic parts. PREPARATION:An alkali metallic salt of a compound shown by formula I is reacted with a halogenated ammonium salt shown by formula II (X is halogen l R5 to R8 are H or OH; with the proviso that R5=R6=R7=R8 H) to give the above-mentioned novel substance.
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机译：新材料：四硫富瓦烯衍生物，其中式I所示化合物的至少一个羧基（R 1至R 4为H或羧基，但不同时为H）形成N-烃基取代的铵盐）。实施例：四硫富瓦戊酸-2,3,6,7-四羧酸二（四正丁基铵）盐。用途：通过直接法可在短时间内通过简单的操作获得的导电电荷转移络合物，可用作电子供体，即使在粉末状态下也可提供具有高导电性的电荷转移络合物，并通过与电子受体反应而提供络合物，最好使用作为电子零件的导电材料。制备：使式I所示的化合物的碱金属盐与式II所示的卤化铵盐反应（X为卤素，R 5至R 8为H或OH;条件是R 5 ≥R6 ＝ R 7 ＝ R 8 H）得到上述新型物质。
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