首页> 外国专利> PROCESS FOR APPLYING A SOLUTION TO A POLYMERIC MESH MATERIAL; HYDROPHYLIC COATING AND TITANIUM DIOXIDE TRANSLUCID; AND PROCESS TO APPLY A HYDROPHILIC COATING TO THE SURFACE OF A SUBSTRATE

PROCESS FOR APPLYING A SOLUTION TO A POLYMERIC MESH MATERIAL; HYDROPHYLIC COATING AND TITANIUM DIOXIDE TRANSLUCID; AND PROCESS TO APPLY A HYDROPHILIC COATING TO THE SURFACE OF A SUBSTRATE

机译:将溶液应用于聚合物网状材料的过程;亲水涂层和二氧化钛过氧化物;底物表面涂亲水涂层的方法和步骤

摘要

A process for treating the surfaces of a polymeric mesh material for use as a separator in an electrochemical cell between an anode and a membrane to obtain a hydrophilic coating comprises (a) removing surface contaminants from the mesh material; (b) contacting the polymeric mesh material with an aqueous acidic titanium halide solution made by mixing together water, a surfactant, titanium halide and an acid collected from HCl, HBr, HF to form an intermediate acidic titanium halide solution and then adding an alkali metal hydroxide to this solution until the pH is about 3.0 to about 4.0; (c) drying the titanium halide solution onto the surface of the polymeric mesh material to form a coating thereon; and (d) converting the coating to a titanium dioxide layer by contacting the coating with an oxidizing agent such as sodium hypochlorite, calcium hypochlorite, hydrogen peroxide and chlorine dioxide. A hydrophilic coating is obtained without the traditional addition of a surfactant to the electrolyte or coating the separator's polymeric surfaces with a surfactant.
机译:处理用作阳极和膜之间的电化学电池中的隔板的聚合物网状材料的表面以获得亲水涂层的方法包括:(a)从网状材料中除去表面污染物; (b)使聚合物筛网材料与酸性卤化钛水溶液接触,该水溶液通过将水,表面活性剂,卤化钛和从HCl,HBr,HF中收集的酸混合在一起形成中间酸性卤化钛溶液,然后加入碱金属在该溶液中加入氢氧化物直至pH为约3.0至约4.0; (c)将卤化钛溶液干燥到聚合物网状材料的表面上以在其上形成涂层; (d)通过使涂层与氧化剂如次氯酸钠,次氯酸钙,过氧化氢和二氧化氯接触使涂层转变成二氧化钛层。无需传统的向电解质中添加表面活性剂或用表面活性剂涂覆隔膜的聚合物表面即可获得亲水涂层。

著录项

  • 公开/公告号BR8803772A

    专利类型

  • 公开/公告日1989-02-21

    原文格式PDF

  • 申请/专利权人 OLIN CORPORATION;

    申请/专利号BR19888803772

  • 发明设计人 DAVID WILLIAM CAWLFIELD;

    申请日1988-07-29

  • 分类号C25B13/04;

  • 国家 BR

  • 入库时间 2022-08-22 06:40:29

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