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PROCESS FOR THE PRODUCTION OF PERFLUOROAL CYLL GROUPS, EPICHLORHYDREDROUPPES AND DIALCOOH RETURN CONTAINING URETHANES AND THEIR USE
PROCESS FOR THE PRODUCTION OF PERFLUOROAL CYLL GROUPS, EPICHLORHYDREDROUPPES AND DIALCOOH RETURN CONTAINING URETHANES AND THEIR USE
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机译:含尿烷的全氟环戊基,表皮重塑和二元醇的生产过程及其用途
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摘要
The novel urethanes, in addition to at least one perfluoroalkyl group, also contain epichlorohydrin groups and dialcohol radicals in the molecule. They are prepared by reacting a fluorine-containing alcohol with epichlorohydrin to give the perfluoroalkyl-epichlorohydrin adduct, reacting this adduct with a di- or triisocyanate to give the perfluoroalkyl-epichlorohydrin-isocyanate adduct and by reacting this adduct with a dialcohol or a monoetherified dialcohol to give the desired urethanes having a perfluoroalkyl group and having epichlorohydrin groups and dialcohol radicals, and by reacting a suitable urethane compound of this type with a perfluoroalkyl-containing di- or triisocyanate to give the desired urethanes having a plurality of perfluoroalkyl groups and having epichlorohydrin groups and dialcoholradicals. The novel urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles.
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