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PRODUCTION OF STRONGLY ACIDIC CATION EXCHANGE FIBER

机译:生产强酸阳离子交换纤维

摘要

PURPOSE:To obtain easily and economically the title fiber which is suitable for use in air and liquid filters, has excellent strength, ion exchange rate (adsorptivity) and heat resistance and is of high quality, by treating a specified fibrous molding with gaseous sulfuric anhydride. CONSTITUTION:A fibrous molding (A) having a fineness of 0.1-500de (e.g., multi-core sea-island type), mainly composed of a major proportion of a poly (arom. monovinyl compd.) composed of a (co)polymer of (alpha-methyl)styrene, vinyltoluene, vinylnaphthalene, p-chlorostyrene, etc., a graft copolymer thereof or a blend thereof and a minor proportion of a reinforcing polymer (e.g., a polyester, a polyamide, a poly-alpha-olefin) is sulfonated and simultaneously crosslinked in an atmosphere contg. 0.1-90% gaseous sulfuric anhydride (B) to obtain the title fiber having an introduced sulfo group content of 0.1-10meq/g of dry molding and a degree of hydration of 0.1-10 which is a measure of a degree of crosslinking.
机译:目的:通过用气态硫酸酐处理特定的纤维模制品,以轻松,经济地获得适用于空气和液体过滤器的标题纤维,具有出色的强度,离子交换率(吸附性)和耐热性,并具有高品质。组成:纤度为0.1-500de(例如,多芯海岛型)的纤维模制品(A),主要由主要部分由(共)聚合物组成的聚(芳族单乙烯基化合物)组成(α-甲基)苯乙烯,乙烯基甲苯,乙烯基萘,对氯苯乙烯等,它们的接枝共聚物或它们的混合物和少量增强聚合物(例如聚酯,聚酰胺,聚α-烯烃)的混合物)在连续的气氛中被磺化并同时交联。得到0.1-90%的气态硫酸酐(B),得到标题纤维,其引入的磺基含量为干模制品的0.1-10meq / g,水合度为交联度的0.1-10。

著录项

  • 公开/公告号JPS63108039A

    专利类型

  • 公开/公告日1988-05-12

    原文格式PDF

  • 申请/专利权人 TORAY IND INC;

    申请/专利号JP19860251899

  • 申请日1986-10-24

  • 分类号B01J47/12;C08J5/20;D06M11/00;D06M11/51;D06M11/55;D06M23/06;D06M101/00;D06M101/16;D06M101/18;D06M101/20;

  • 国家 JP

  • 入库时间 2022-08-22 07:08:22

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