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Heteropolymetallic clusters, methods of making such clusters, and catalysts utilizing such clusters
Heteropolymetallic clusters, methods of making such clusters, and catalysts utilizing such clusters
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机译:杂多金属团簇,制备此类团簇的方法以及利用此类团簇的催化剂
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摘要
Heteropolymetallic clusters of the formula Pd.sub.2 (Fe).sub.x (CO). sub.4 CO(NO).sub.2 !.sub.y bis(diphenylphosphine)methane!.sub.2 wherein x is 1 or 2 and y is 0 or 1; x=2 when y=1 and x=1 when y=0; to the method of making such clusters by reacting Pd.sub.2 Cl.sub.2 bis(diphenylphosphine)methane! with MnFe(CO).sub.3 Z wherein M is an alkaline metal and Z is CO (n=2) or NO (n=1); and to the novel catalysts formed utilizing said clusters.
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