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Heteropolymetallic clusters, methods of making such clusters, and catalysts utilizing such clusters

机译:杂多金属团簇,制备此类团簇的方法以及利用此类团簇的催化剂

摘要

Heteropolymetallic clusters of the formula Pd.sub.2 (Fe).sub.x (CO). sub.4 CO(NO).sub.2 !.sub.y bis(diphenylphosphine)methane!.sub.2 wherein x is 1 or 2 and y is 0 or 1; x=2 when y=1 and x=1 when y=0; to the method of making such clusters by reacting Pd.sub.2 Cl.sub.2 bis(diphenylphosphine)methane! with MnFe(CO).sub.3 Z wherein M is an alkaline metal and Z is CO (n=2) or NO (n=1); and to the novel catalysts formed utilizing said clusters.
机译:式Pd.sub.2(Fe).sub.x(CO)的杂多金属簇。 sub.4 CO(NO)2sub.y bis(diphenylphosphine)methane!2,其中x为1或2,y为0或1;当y = 1时x = 2,当y = 0时x = 1;通过使Pd.sub.2 Cl.sub.2双(二苯基膦)甲烷反应来制备这种簇的方法! MnFe(CO)3 Z,其中M是碱金属,Z是CO(n = 2)或NO(n = 1);以及利用所述簇形成的新型催化剂。

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