首页> 外国专利> DENSE ANODO, RECHARGEABLE ELECTROCHEMICAL BATTERY IN UNLOADED CONDITION AND PROCESS FOR THE PREPARATION OF ELECTROCHEMICAL BATTERY IN LOADED CONDITION

DENSE ANODO, RECHARGEABLE ELECTROCHEMICAL BATTERY IN UNLOADED CONDITION AND PROCESS FOR THE PREPARATION OF ELECTROCHEMICAL BATTERY IN LOADED CONDITION

机译:浓阳极阳极,可充电电化学电池在空载条件下的制备方法及在负载条件下制备电化学电池的过程

摘要

The disclosure describes an anode made of a thin metallic foil in discharged condition which is converted into a dense metallic alloy of an alkali metal during the first charge. The disclosure also describes an electrochemical rechargeable battery in discharged condition. The latter comprises an anode made of a thin metallic foil, such as aluminum, magnesium or tin, an electrolyte, for example a polymeric electrolyte, as well as a cathode based on an oxide, a sulfide or an halide, prepared in discharged condition and constituting a source of alkali metal preferably lithium. The cathode should be capable of freeing the alkali metal under a charge so that the latter is introduced into the metallic foil to form an alloy of the alkali metal and of at least a portion of the metal constituting the metallic sheet. To obtain the charged battery, it is merely sufficient to apply a charge during a certain period of time while the anode is being transformed into an alloy. Substantially improved properties during cycling.
机译:本发明描述了一种由处于放电状态的薄金属箔制成的阳极,该阳极在第一次充电期间被转化为碱金属的致密金属合金。本发明还描述了处于放电状态的电化学可充电电池。后者包括由薄金属箔(例如铝,镁或锡)制成的阳极,电解质(例如聚合物电解质)以及基于氧化物,硫化物或卤化物的阴极,该阴极在放电条件下制备并构成碱金属源,优选锂。阴极应该能够在电荷的作用下释放碱金属,以便将碱金属引入金属箔中,以形成碱金属和构成金属片的至少一部分金属的合金。为了获得充电的电池,仅需在阳极转变成合金的一定时间内施加电荷即可。循环过程中的性能大大改善。

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