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Picosecond broadband cars probe using the picosecond continuum

机译:皮秒级宽带汽车使用皮秒连续体进行探测

摘要

A coherent anti-Stokes Raman spectroscopy (CARS) method and apparatus for producing a broadband CARS vibrational spectrum of a sample in a single picosecond laser pulse. A laser pulse having a picosecond duration and a frequency of &ohgr; is directed into a liquid cell containing D. sub.2 O which generates a picosecond continuum pulse having a broad range of frequencies &ohgr;.sub.WL and a picosecond duration. A second harmonic of the laser pulse is produced to form a probe pulse having a frequency of &ohgr;.sub.1 and a picosecond duration. The probe pulse and the continuum pulse are spatially and temporally combined and the combined pulses are directed into a sample to excite the Raman active vibrational resonances in the sample. In response the sample emits a beam of radiation which contains an anti-Stokes spectrum of energy characteristic of the sample. The anti-Stokes spectrum is separated from the beam of radiation for detection and analysis.
机译:用于在单个皮秒激光脉冲中产生样品的宽带CARS振动谱的相干反斯托克斯拉曼光谱(CARS)方法和设备。激光脉冲的持续时间为皮秒,频率为&ohgr; “ D.sub.O”被引导到包含D.sub。2 O的液池中,该液池产生皮秒连续脉冲,该脉冲具有宽范围的ωWL和皮秒持续时间。产生激光脉冲的二次谐波以形成探测脉冲,该探测脉冲具有≤1的频率和皮秒的持续时间。探测脉冲和连续脉冲在空间和时间上进行组合,并将组合后的脉冲定向到样本中,以激发样本中的拉曼主动振动共振。作为响应,样品发射一束辐射,该束包含样品的能量特性的反斯托克斯光谱。反斯托克斯光谱与辐射束分开进行检测和分析。

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