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Process for dyeing fiber material made of natural polyamides with anionic wool dyes at pH 4.5 to 5.5 in the presence of a dyeing assistant

机译:在染色助剂存在下用pH 4.5至5.5的阴离子羊毛染料将天然聚酰胺制成的纤维材料染色的方法

摘要

The invention relates to a process for the non-skittery and level dyeing of fibre material made of natural polyamides, with dyes or mixtures of dyes in the presence of a mixture of dyeing assistants, which comprises using for dyeing these materials an aqueous liquor which contains at least one anionic wool dye which, under the defined dyeing conditions at 1/1 standard depth, exhausts to at least 95%, and a dyeing assistant mixture containing an anionic compound of the formula ##STR1## in which R is an alkyl or alkenyl radical having 12 to 22 carbon atoms, M is hydrogen, an alkali metal or ammonium, and m and n are integers such that the sum of m and n is 2 to 14, a quaternary compound of the formula ##STR2## in which R', independently of R, is what R has been defined as, A is an anion, Q is a substituted or unsubstituted alkyl radical, and p and q are integers such that the sum of p and q is 20 to 50 , and a non- ionic compound of the formula ##STR3## in which R", independently of R, is what R has been defined as, and x and y are integers such that the sum of x and y is 80 to 140, and which liquor can, if desired, also contain an ammonium or alkali metal salt, and finishing the dyeing regardless of its depth at pH 4.5-5.5 and at a temperature of 95 to 105 C. The process according to the invention is suitable for dyeing natural polyamide materials, especially wool, but also wool/nylon, wool/polyester, wool/cellulose or wool/polyacrylonitrile blends and silk, giving, with various types of dye or mixtures of dyes of identical or different dye types, non-skittery and level dyeings having good fastness properties.
机译:本发明涉及一种由天然聚酰胺制成的纤维材料在染料助剂混合物的存在下与染料或染料混合物进行的非匀速匀整染色的方法,该方法包括使用将含有至少一种阴离子羊毛染料,其在规定的染色条件下以1/1标准深度排尽至至少95%,以及一种染色助剂混合物,其中所述通式为## STR1 ##的阴离子化合物,其中R为烷基或具有12至22个碳原子的烯基基团,M为氢,碱金属或铵,并且m和n为整数,使得m和n的总和为2至14,是式## STR2 ##的季化合物其中R'独立于R,是R的定义,A是阴离子,Q是取代或未取代的烷基,p和q是使得p和q之和为20至50的整数。和式## STR3 ##的非离子化合物,其中R“独立于R,i s R的定义为,x和y是整数,使得x和y的总和为80至140,并且如果需要,哪种溶液还可以包含铵盐或碱金属盐,并且无论其深度在pH 4.5-5.5和温度95-105 C时。本发明的方法适用于染色天然聚酰胺材料,尤其是羊毛,但也适合羊毛/尼龙,羊毛/聚酯纤维,羊毛/纤维素或羊毛/聚丙烯腈共混物和丝绸,用各种类型的染料或相同或不同染料类型的染料混合物制成具有良好坚牢度特性的不滑腻和匀染的染料。

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