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Process for producing oil-soluble derivatives of unsaturated C. sub.4 -C. sub.10 dicarboxylic acid materials

机译:制备不饱和C.sub.4-C的油溶性衍生物的方法。 sub.10二元羧酸材料

摘要

An improved process for preparing oil-soluble derivatives of unsaturated C.sub.4 -C.sub.10 dicarboxylic acid materials, e.g. the product of the reaction of polyisobutylene and maleic anhydride, under Ene reaction conditions characterized in that said Ene reaction is conducted under acidic conditions as by conducting said reaction in the presence of from 0.01 to 5 wt. %, based on total weight of the reactants, of an oil-soluble strong organic acid containing a hydrogen dissociating moiety which has a pK of less than about 4.0, as exemplified by a C.sub. 15 to C.sub.76 hydrocarbyl-substituted sulfonic acid, whereby sediment resulting from said Ene reaction is markedly reduced to less than 1 wt. %.
机译:制备不饱和C 4 -C 10二元羧酸材料的油溶性衍生物的改进方法,例如在Ene反应条件下,聚异丁烯与马来酸酐反应的产物,其特征在于,所述Ene反应在酸性条件下进行,如在0.01-5wt。%的存在下进行所述反应。以反应物的总重量为基准计,%的油溶性强有机酸包含氢解离部分,其pK小于约4.0,例如C。 15至C.sub.76烃基取代的磺酸,由此所述Ene反应产生的沉淀物显着减少至小于1wt。%。 %。

著录项

  • 公开/公告号US4235786A

    专利类型

  • 公开/公告日1980-11-25

    原文格式PDF

  • 申请/专利权人 EXXON RESEARCH AND ENGINEERING;

    申请/专利号US19790080939

  • 发明设计人 MAX J. WISOTSKY;

    申请日1979-10-01

  • 分类号C07D307/60;

  • 国家 US

  • 入库时间 2022-08-22 14:51:44

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