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PROCESS FOR REMOVING TRITIUM FROM TRITIUM-CONTAINING HEAVY WATER TO RECOVER TRITIUM GAS OF HIGH PURITY

机译:从含RIT的重水中去除T以回收高纯RIT气的方法

摘要

Abstract of the Disclosure:A process is, herein, disclosed for removing tritiumfrom tritium-containing heavy water to recover tritium gasof high purity characterized by feeding a part of the heavywater containing tritium from a source for supplying theheavy water such as heavy water moderated power reactor toan exchange reaction column wherein the heavy water contactswith deuterium gas countercurrently, extracting heavy waterenriched in tritium from the bottom of the exchange reactioncolumn and converting it to vapor of heavy water, passingthe vapor of heavy water through at least one packed columnof two columns packed with easily oxidizable or reduciblemetals by steam or hydrogen respectively wherein the metalin the column is oxidized to metal oxide while the vaporof heavy water is reduced to deuterium gas, recycling mostof the deuterium gas to the exchange reaction column toeffect countercurrent contact between heavy water anddeuterium gas, extracting the deuterium gas of reduced tri-tium content from the top of the exchange reaction column,passing said deuterium gas through the other column in whichthe metal packed has already been oxidized to metal oxidewherein the metal oxide is reduced to metal while thedeuterium gas is oxidized to heavy water and recycling apart of the heavy water of reduced tritium content to theheavy water supplying source while recycling the residualheavy water to the top of the exchange reaction column,introducing a part of the gas obtained after passing thevapor of heavy water through the heated metal layer to thethermal diffusion column cascade and concentrating thetritium to recover the tritium as tritium gas of high purity.- 1 -
机译:披露摘要:本文公开了一种去除tri的方法从含tri的重水中回收tri气具有高纯度,其特点是喂入了一部分重油含有tri的水源诸如重水调节动力堆等重水交换反应塔,其中重水接触与氘气逆流提取重水从交换反应的底部富集了tri柱并将其转化为重水蒸气,通过通过至少一个填充塔的重水蒸气两列填充有易于氧化或还原的色谱柱金属分别通过蒸汽或氢气,其中金属色谱柱中的金属被氧化成金属氧化物,而蒸气的重水被还原为氘气,大部分被回收氘气进入交换反应塔使重水与氘气,提取还原三重氘气交换反应塔顶部的含量使所述氘气通过另一塔,其中包装好的金属已经被氧化成金属氧化物其中金属氧化物被还原为金属,而氘气被氧化成重水并循环利用the含量降低的部分重水重水供应源,同时回收剩余物重水到交换反应塔的顶部,引入一部分通过后获得的气体重水蒸气通过加热的金属层到达热扩散塔级联并浓缩to以高纯度的gas气形式回收recover。-1-

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