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Crystalline arsenic silicate zeolite useful as catalyst - e.g. in methanol conversion to olefin cpd., is produced by hydrothermal synthesis from silica and arsenic tri:oxide
Crystalline arsenic silicate zeolite useful as catalyst - e.g. in methanol conversion to olefin cpd., is produced by hydrothermal synthesis from silica and arsenic tri:oxide
New crystalline As silicate (I) has zeolite structure. (I) is produced by heating SiO2 and As2O3 in an aq. hexamethyl-enediamine (II) soln. at 100-200 degrees C under autogenous pressure and crystallisation. (I) is useful as catalyst in hydrocarbon conversions, esp. in the conversion of MeOH (or Me2O) to (2-4C) olefins.
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机译:新的结晶态硅酸盐(I)具有沸石结构。 (I)是通过在水溶液中加热SiO 2和As 2 O 3制备的。六甲基烯二胺(II)溶液。在自生压力和结晶下在100-200摄氏度下进行。 (I)特别是在烃转化中用作催化剂。在MeOH(或Me 2 O)到(2-4C)烯烃的转化中反应。
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