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Polybrominated fire-retardants for plastics - poly (tribromophenoxymethylene) polymethyl benzenes

机译:塑料用多溴阻燃剂-聚三溴苯基亚甲基聚甲基苯

摘要

Novel tribromophenoxymethylene benzenes of formula (I): (m = 2-4; m+n = 6) are prepd. by reacting bromoethylated benzenes with tribromophenol in presence of base in acetone-toluene. (I) are flame-protectants for plastics. for thermoplastics, esp. high-density polyethylene, 1,2,4,5-tetramethyl-3,6-bis(2,4,6-tribromophenoxymethylene)benzen- e (Ia) and 1,3,5-trimethyl-2,4,6-tris(2,4,6-tribromophenoxymethylene)benzene (Ib) are pref. and are used at 2-10, esp. 3-5 wt. %. They are readily incorporated into the molten plastics without decompsn. and have no tendency to migrate.
机译:制备式(I)的新的三溴苯氧基亚甲基苯:(m = 2-4; m + n = 6)。在丙酮-甲苯中,在碱的存在下,使溴乙基苯与三溴苯酚反应。 (I)是塑料的阻燃剂。用于热塑性塑料,特别是高密度聚乙烯,1,2,4,5-四甲基-3,6-双(2,4,6-三溴苯氧基亚甲基)苯(ea)和1,3,5-三甲基-2,4,6-三(2,4,6-三溴苯氧基亚甲基)苯(Ib)优选。且使用时间为2-10,尤其是。 3-5 wt。 %。它们可以很容易地掺入熔融塑料中而无需分解。并且没有迁移的趋势。

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