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REDUCTION OF SO2 CONTENT OF AN SO2-CONTAINING GAS

机译:减少含SO2气体中SO2含量

摘要

1314332 Removing sulphur dioxide from gas mixtures ESSO RESEARCH & ENG CO 15 May 1970 [28 May 1969] 27024/69 Headings B1L and B1R [Also in Divisions C1 C5 and F4] The SO 2 content of gases made from partial or complete combustion processes or derived from ore-roasting processes is reduced by contacting the gases with a hydrocarbon oil, e.g. fuel oils, distillates, catalytic fuel oils and mixtures thereof, at a temperature ranging from 400‹ to 800‹F. The gases may be bubbled through the oil, see Fig. 2 (not shown) or passed in countercurrent to a spray of the oil in an empty or packed vessel, see Fig. 3 (not shown). An alumina catalyst for promoting the reaction of SO 2 with H 2 S may be included in the oil in the embodiment of Fig. 2 or form the packing in the embodiment of Fig. 3, or be located in a separate vessel downstream of the gas and oil contacting vessel. Additional SO 2 - containing gas, e.g. a portion of the gas to be purified, may be combined with the treated gas, e.g. in the catalyst-containing vessel, to react wtih excess H 2 S. The purified gas may be contacted with a fluidised bed of an alkaline earth metal oxide or carbonate, see Fig. 5 (not shown) to remove traces of SO 2 .
机译:1314332从混合气体中去除二氧化硫ESSO RESEARCH&ENG CO 1970年5月15日[1969年5月28日] 27024/69标题B1L和B1R [也在C1,C5和F4分区中]部分或完全燃烧过程或通过使气体与烃油(例如:燃料油,馏出物,催化燃料油及其混合物,温度范围为400°F至800°F。气体可以通过油鼓泡(见图2)(未显示),也可以与油的喷雾逆流通过空的或装满的容器(见图3)(未显示)。用于促进SO 2与H 2 S反应的氧化铝催化剂可包含在图2的实施方案中的油中,或形成在图3的实施方案中的填料,或位于气体下游的单独容器中和油接触容器。额外的含SO 2气体,例如一部分要纯化的气体可以与处理过的气体例如在含催化剂的容器中,H 2 S与过量的H 2 S反应。纯化的气体可以与碱土金属氧化物或碳酸盐的流化床接触,见图5(未显示)以除去痕量的SO 2。

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