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A method for the selective registration of more compartment quanta - by means of turns in the case of nuclear magnetic resonance (nuclear magnetic resonance)

机译:一种选择性地记录更多部分量子的方法-在核磁共振(核磁共振)情况下通过轮流进行

摘要

Selected orders of multiple quantum transitions may be detected by preparing a statistical non-equilibrium state of an assembly of gyromagnetic resonators of selected phase with respect to a subsequent mixing pulse. After an evolution period, t.sub.1, a 90° mixing pulse is applied and the free induction decay is sampled as a function of time, t.sub.2. The signal functions S.sub.i (t.sub.1, t.sub.2, &phgr;.sub. i) is developed for systematically varied values of t.sub.1 and specially selected values of &phgr;.sub.i. Linear combinations of the signal functions S.sub.i yield, after Fourier transformation a two dimensional spectrum of multiple quantum transitions limited by the choice of phase and linear combination. In another embodiment, a magnetic gradient pulse is applied during the evolution period and resulting multiple quantum transitions yield spectral peaks of width dependent upon the order of such transitions. In particular, all spectral peaks may be removed from resulting spectra save only zero order transitions.
机译:通过准备相对于随后的混合脉冲的选定相位的旋磁谐振器的组件的统计非平衡状态,可以检测多个量子跃迁的选定阶数。在演化周期t.sub.1之后,施加90°的混合脉冲,并随时间t.sub.2采样自由感应衰减。信号函数Si(t.sub.1,t.sub.2,ph.sub.i)是针对系统变化的t.sub.1值和phgr.sub的特殊选择值而开发的。一世。信号函数Si的线性组合在傅立叶变换后产生多个量子跃迁的二维频谱,该二维频谱受到相位和线性组合的选择的限制。在另一个实施例中,在演化周期期间施加磁梯度脉冲,并且所产生的多个量子跃迁产生宽度取决于这种跃迁的顺序的光谱峰。特别地,所有光谱峰可以从得到的光谱中去除,仅保留零级跃迁。

著录项

  • 公开/公告号DE2847641A1

    专利类型

  • 公开/公告日1979-05-31

    原文格式PDF

  • 申请/专利权人 VARIAN ASSOCIATES;

    申请/专利号DE19782847641

  • 发明设计人 ERNST RICHARD R;

    申请日1978-11-02

  • 分类号G01N27/78;

  • 国家 DE

  • 入库时间 2022-08-22 19:43:36

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