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how przeksztalcania chiralowego acid ester of optically activedrugorzedowym alcohol alpha - cyjanowym configuration (r) in chiralowego acid ester with alcohol drugorzedowym alpha - cyjanowym configuration (s)
how przeksztalcania chiralowego acid ester of optically activedrugorzedowym alcohol alpha - cyjanowym configuration (r) in chiralowego acid ester with alcohol drugorzedowym alpha - cyjanowym configuration (s)
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机译:如何将手性酸酯中的光活化仲醇α-氰基构型的手性氨基酸转化为醇仲α-氰基ow构型(s)
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摘要
A process for the preparation of an ester of chiral (A) acid with an optically active (S) alpha -cyano-3-phenoxybenzyl alcohol by reacting an ester of chiral (A) acid with alpha -cyano-3-phenoxybenzyl alcohol of the formula IMAGE B in its optically active (R) form or a racemic (R,S) mixture or a mixture of esters of said (R) alcohol and (S) alcohol in non-equimolecular proportions designated herein as "ester (R+S)" with a base selected from the group consisting of ammonium hydroxide, primary, secondary and tertiary amines, quaternary ammonium compounds, liquid amines of high molecular weight, ion exchange resins of a basic character and a catalytic amount of a strong base in at least one solvent in which the ester of the (R) alcohol is soluble and in which the ester of the (S) alcohol is insoluble and recovering from the resulting medium the chiral (A) acid ester of the (S) alcohol which is insoluble.
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