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Process for preparing elastomeric copolymers of ethylene and higher alpha- olefins

机译:乙烯和高级α-烯烃的弹性体共聚物的制备方法

摘要

High yields of elastomeric copolymers of ethylene and higher alpha- olefins, or of ethylene, higher alpha-olefins and unsaturated monomers (polyenes) containing two or more double bonds are obtained by copolymerizing a mixture of the monomers in contact with a catalyst prepared by mixing a catalyst- forming component which is an organometallic compound of aluminum with a supported catalyst-forming component obtained by contacting a halogenated titanium compound with a carrier or support consisting of or comprising an anhydrous Mg or Mn halide partially or completely complexed with a Lewis base capable of forming a complex with it.PPThe copolymers so obtained have valuable mechanical properties, in particular a relatively low value of permanent set and do not exhibit excessive residual deformation at break.
机译:通过使单体的混合物与通过混合制备的催化剂接触共聚,可获得高收率的乙烯和高级α-烯烃的弹性体共聚物,或乙烯,高级α-烯烃和含有两个或多个双键的不饱和单体(多烯)的弹性体共聚物。催化剂形成组分,其为铝与负载的催化剂形成组分的有机金属化合物,所述催化剂形成的组分通过使卤化的钛化合物与由或部分与无水Mg或Mn卤化物组成或包含无卤Mg或Mn的载体或载体接触而制得如此获得的共聚物具有有价值的机械性能,特别是相对较低的永久形变值,并且不表现出过度的断裂残余变形。

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