首页> 外国专利> Then make the entire top surface of plate to chemical treatment by making to flatten wooden board again to mechanical treatment for the manufacturing method with historical relics or the timber floor plate seen used

Then make the entire top surface of plate to chemical treatment by making to flatten wooden board again to mechanical treatment for the manufacturing method with historical relics or the timber floor plate seen used

机译:然后,对木板的整个上表面进行化学处理,方法是将木板再次压平以进行机械处理,以使用历史文物或所用的木地板进行制造

摘要

Hydrogenation of the exocyclic methylene gp. of a 6-deoxy-6-demethyl-6-methylene-tetracycline (I), or its acid addition salt, in a stereoselective manner giving the alpha-isomer in preference to the beta-isomer, is carried out at 20-100 degrees C and 1-100 atmos. under neutral conditions, or using a weakly acidic acid addn. salt, in the presence of a catalytic amt. of a cpd. of formula Rh(OCOR)2(P C6H5 3) (II) (where R = H, 1-6C alkyl, ClCH2, Cl2CH, Cl3C, FCH2, F2CH, F3C, phenyl, chlorphenyl, tolyl, anisyl). The ratio of alpha-isomer to beta-isomer is =9:1. Known methods give a less favourable ratio e.g. 1:1.
机译:外环亚甲基gp的氢化。在20-100度下进行立体选择性的6-脱氧-6-脱甲基-6-亚甲基四环素(I)或其酸加成盐的制备,使α-异构体优先于β-异构体C和1-100 atmos。在中性条件下,或使用弱酸性添加剂。在催化氨的存在下cpd。式Rh(OCOR)2(P C 6 H 5 3)(II)的化合物(其中R = H,1-6C烷基,ClCH 2,Cl 2 CH,Cl 3 C,FCH 2,F 2 CH,F 3 C,苯基,氯苯基,甲苯基,茴香基)。 α-异构体与β-异构​​体的比例≥9∶1。已知的方法给出了较差的比率,例如。 1:1

著录项

  • 公开/公告号NO754085A

    专利类型

  • 公开/公告日1976-06-22

    原文格式PDF

  • 申请/专利权人 PFIZER INC;

    申请/专利号NO19750004085

  • 发明设计人 FAUBL H;

    申请日1975-12-03

  • 分类号C07C103/19;

  • 国家 NO

  • 入库时间 2022-08-23 02:48:06

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