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PREPARATION OF TRICYCLOHEXYLIDENE TRIPEROXIDE OR A MIXTURE OF DICYCLOHEXYLIDENE DIPEROXIDE AND TRICYCLOHEXYLIDENE TRIPEROXIDE
PREPARATION OF TRICYCLOHEXYLIDENE TRIPEROXIDE OR A MIXTURE OF DICYCLOHEXYLIDENE DIPEROXIDE AND TRICYCLOHEXYLIDENE TRIPEROXIDE
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机译：三环己烯三氧化物的制备或二环己烯二氧化物和三环己烯三氧化物的混合物
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1347853 Tricyclohexylidenetriperoxide and dicyclohexylidene diperoxide STORY CHEMICAL CORP 28 June 1971 [29 June 1970] 30192/71 Heading C2C Tricyclohexylidene triperoxide is obtained by treating 1-hydroperoxy- 1SP1/SP-hydroxydicyclohexyl peroxide or 1,1SP1/SP-dihydroperoxydicyclohexyl peroxide with a liquid carboxylic acid and a strong acid catalyst. Alternatively a mixture of tricyclohexylidene triperoxide and dicyclohexylidene diperoxide is obtained by treating the above mentioned starting materials with a strong acid catalyst in the presence of an organic solvent. Suitable strong acids are, for example, hydrochloric acid, sulphuric acid, perchloric acid, p-toluene sulphonic acid, nitric acid and sulphuric acid. Suitable carboxylic acids are, for example, formic acid, propionic acid, acetic acid and butyric acid. Suitable organic solvents are, for example, pentane, hexane, benzene, toluene, xylene, ether, carbon tetrachloride, chloroform, cyclohexane, heptane, decane, cyclodecane, nonane, undecane, dodecane and acetonitrile.
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机译：1347853三环己基过氧化二氧化物和二环己基二过氧化二氧化物STORY CHEMICAL CORP 1971年6月28日[1970年6月29日] 30192/71标题C2C三环己基三过氧化三氧化物是通过处理1-氢过氧-1 1 -羟基二环己基过氧化物或1,1 获得的1 -二氢过氧二环己基过氧化物与液体羧酸和强酸催化剂或者，通过在有机溶剂存在下用强酸催化剂处理上述起始原料，得到三环己基三过氧化物和二环己基二过氧化物的混合物。合适的强酸是例如盐酸，硫酸，高氯酸，对甲苯磺酸，硝酸和硫酸。合适的羧酸是例如甲酸，丙酸，乙酸和丁酸。合适的有机溶剂是例如戊烷，己烷，苯，甲苯，二甲苯，醚，四氯化碳，氯仿，环己烷，庚烷，癸烷，环癸烷，壬烷，十一烷，十二烷和乙腈。
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