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Method and apparatus for independent regulation of the minimum of the sum of the concentrations of hydrogen sulfide and sulfur dioxide is used in the residual gases of units for sulfur recovery

机译:在硫磺回收装置的残余气体中使用独立调节硫化氢和二氧化硫浓度之和的最小值的方法和设备

摘要

988, 642. Infra-red analysis. SOC.NATIONALE DES PETROLES D'AQUITAINE. Feb. 21, 1963 [Feb. 22, 1962], No. 7007/ 63. Heading G1A. [Also in Division G3] In a system for automatically controlling a sulphur recover-process involving the oxidation of H 2 S (see Division G3) the effluent gas is continuously sampled and tested by an infra absorption red analyser. Dual pumps 12 suck in equal volumes of air and effluent which are discharged in a first phase, directly to the analyser, and in a second phase through a catalytic oxidation furnace 15 where the H 2 S is oxidised to SO 2 before analysis. In the analyser to eliminate the effect of any CO 2 which may be present a filter 19 of pure CO 2 between the infra-red source 16 and test cell 17 absorbs in the 4.2 to 4.5 micron band, which overlaps a weak SO 2 absorption in the 3.9 to 4.5 micron band. SO 2 is estimated in the first measurement since it has a high absorption in the 7-9. 5 micron band and the weak effect of H 2 S in the 7-8. 5 micron band may be neglected to an accuracy of 0.3%. During the second measurement, the increase in SO 2 due to oxidation of H 2 S in furnace 15 represents the H 2 S measurement. These measurements appear as D.C. output signals from receiver 18 and are fed-through amplifier 22 to the recorder, IV. The recorder drives a synchro transmitter supplying signals to the automatic control system.
机译:988,642。红外分析。法国国家石油公司阿奎塔因。 1963年2月21日[Feb. [1962年12月22日],第7007/63号。标题G1A。 [也属于G3分部]在用于自动控制涉及H 2 S氧化的硫回收过程的系统中(请参见G3分部),对流出的气体进行连续采样,并通过红外吸收红色分析仪进行测试。双泵12吸入等体积的空气和流出物,它们在第一阶段中直接排放到分析仪中,并在第二阶段中通过催化氧化炉15排放,在此之前,H 2 S在分析之前被氧化成SO 2。在分析仪中,为了消除可能存在的任何CO 2的影响,红外源16和测试单元17之间的纯CO 2过滤器19在4.2到4.5微米的波段内吸收,这与弱的SO 2吸收重叠。 3.9至4.5微米波段。由于SO 2在7-9中具有高吸收率,因此在第一次测量中就对其进行了估算。 5微米波段和H 2 S的弱效应在7-8。 5微米的带可以忽略不计,精确度为0.3%。在第二次测量中,由于炉15中H 2 S的氧化而导致的SO 2的增加代表了H 2 S的测量。这些测量结果显示为来自接收器18的直流输出信号,并通过放大器22馈送到记录器IV。记录器驱动一个同步发送器,向自动控制系统提供信号。

著录项

  • 公开/公告号DE1253684B

    专利类型

  • 公开/公告日1967-11-09

    原文格式PDF

  • 申请/专利权人 AQUITAINE PETROLE;

    申请/专利号DE1963S083845

  • 发明设计人 EVANO GILBERT ROGER;

    申请日1963-02-21

  • 分类号B01D53/52;B01J19;C01B17/04;G05B13/02;

  • 国家 DE

  • 入库时间 2022-08-23 14:07:08

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