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Process for converting ferro-phosphorus rich in silicon into ferro-phosphorus of high phosphorus content free from or poor in silicon

机译:将富含硅的磷铁转化为无磷或贫硅的高磷含量的磷铁的方法

摘要

Ferro-phosphorus rich in silicon is converted into ferro-phosphorus poor in or free from silicon and having a high phosphorus content by mixing it, preferably in a fluid state, with tricalcium or other raw phosphate, preferably in excess, say about 50 per cent above the theoretical, and fusing in a non-oxidizing atmosphere, for example in an electric furnace. The phosphate is reduced by the silicon, and the free phosphorus formed is partly taken up by the ferro-phosphorus and partly escapes, being condensed or burnt to phosphoric acid. The silica produced forms a slag with the lime. The reaction commences at about 1450 DEG C. and is completed at 1500-1600 DEG C. The product may contain up to 30 per cent of phosphorus.ALSO:Ferro-phosphorus rich in silicon is converted into ferro-phosphorus free from or poor in silicon and having a high phosphorus content by mixing it, preferably in a fluid state, with tricalcium or other raw phosphate, preferably in excess, say about 50 per cent above the theoretical, and fusing in a non-oxidizing atmosphere, for example in an electric furnace. The phosphate is reduced by the silicon, and the free phosphorus formed is partly taken up by the ferro-phosphorus and partly escapes. The silica produced forms a slag with the lime. The reaction commences at about 1450 DEG C. and is completed at 1500-1600 DEG C. The product may contain up to 30 per cent of phosphorus.
机译:通过将硅(最好是液态)与三钙或其他粗磷酸盐(优选过量,例如约50%)混合,可以将富含硅的铁磷转化为贫硅或不含硅,磷含量高的铁磷。高于理论值,并在非氧化性气氛下(例如在电炉中)熔融。磷酸盐被硅还原,形成的游离磷部分被铁磷吸收,部分逸出,被冷凝或燃烧成磷酸。产生的二氧化硅与石灰形成炉渣。反应在约1450℃开始,并在1500-1600℃完成。该产品可能含有高达30%的磷。ALSO:富含硅的亚铁磷转化为无磷或贫铁的磷铁。硅,并通过将磷(最好呈液态)与三钙或其他粗磷酸盐(优选过量,比理论值高约50%)混合,并在非氧化性气氛(例如在电炉。磷酸盐被硅还原,形成的游离磷部分被铁磷吸收,部分逸出。产生的二氧化硅与石灰形成炉渣。反应在约1450℃开始,并在1500-1600℃完成。该产物可能含有高达30%的磷。

著录项

  • 公开/公告号GB355610A

    专利类型

  • 公开/公告日1931-08-27

    原文格式PDF

  • 申请/专利权人 I. G. FARBENINDUSTRIE AKTIENGESELLSCHAFT;

    申请/专利号GB19300035893

  • 发明设计人

    申请日1930-11-28

  • 分类号C21C7/00;

  • 国家 GB

  • 入库时间 2022-08-24 08:19:54

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