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TETHERED TRANSITION METALS PROMOTED PHOTOCATALYTIC SYSTEM FOR EFFICIENT HYDROGEN EVOLUTIONS
TETHERED TRANSITION METALS PROMOTED PHOTOCATALYTIC SYSTEM FOR EFFICIENT HYDROGEN EVOLUTIONS
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机译：束缚过渡金属促进光催化系统以获得高效的氢气进化
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摘要
The present invention is a photocatalyst by tethering (deposition) a metal (e.g., a late transition metal, such as a metal ion of nickel) to the surface of a semiconductor (photocatalyst) at least in part using an organic ligand. It relates to a method of improving the efficiency of (semiconductor photocatalyst). More specifically, 1,2-ethanedithiol (EDT) is an excellent molecular linker for attaching transition metal complexes (e.g., nickel (Ni 2+ ions)) to the semiconductor surface (e.g., organic Ligand), and the semiconductor surface may be in the form of a cadmium sulfide surface. Photocatalysts are particularly useful for generating hydrogen from H 2 S.展开▼
机译：本发明是至少部分地使用有机配体，通过束缚（沉积）金属（例如，镍的后期过渡金属，例如镍的后期过渡金属）到半导体（光催化剂）的表面。它涉及一种提高（半导体光催化剂）效率的方法。更具体地，1,2-乙基硫醇（EDT）是用于将过渡金属配合物（例如，镍（Ni 2 + / SUP>离子））上的半导体表面（例如，有机配体）的优异分子接头（例如，有机配体），并且半导体表面可以是硫化镉表面的形式。光催化剂特别适用于从 h 2 s产生氢。
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