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CRYSTAL GROWTH OF MUSHY LAYER IN WATER ETHANOL MIXTURE

机译:水乙醇混合液中粘性层的晶体生长。

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摘要

A water ethanol mixture can exist either as a liquid or solid phase. Because of this property, waterrnethanol mixtures are becoming considerably important as an environment friendly coolant or arnthermal storage material. The crystallization in the mixture occurs in two ways: firstly, equiaxedrncrystals grow in the mixture and secondly, crystal growth occurs within the mushy layer, which isrnformed on a refrigerated surface. Here, in order to understand the characteristics of the crystalrngrowth within the mushy layer, the effect of surface temperature on the crystal growth was investigatedrnby varying the concentrations of ethanol and observing the crystal growth in a liquid pool inrncontact with a refrigerated surface. Five types of mushy layers were observed in the solid-liquidrncoexisting region of the water ethanol mixture, and further, three types of crystal growth processrnwere indentified: namely, the formation of a dendric layer, a white layer and a transparent layer atrnvarious surface temperatures and concentrations of ethanol. Additionally, it was found that mushyrnlayer thickness grew in proportion to the 1/2 power of time in the early stages of crystal growth, forrnlow ethanol concentrations.
机译:水乙醇混合物可以液相或固相存在。由于这种特性,水-乙醇混合物作为一种环境友好型冷却剂或低温储热材料变得越来越重要。混合物中的结晶以两种方式发生:第一,等轴晶在混合物中生长,第二,晶体生长在糊状层中,该糊状层在冷藏表面上形成。在此,为了理解糊状层内的晶体生长的特性,通过改变乙醇的浓度并观察与冷藏表面不接触的液池中的晶体生长,研究了表面温度对晶体生长的影响。在水-乙醇混合物的固液共存区域中观察到五种糊状层,此外,确定了三种类型的晶体生长过程:即在不同的表面温度下形成树枝状层,白色层和透明层。乙醇浓度。另外,发现在晶体生长的早期阶段,糊剂层的厚度与时间的1/2幂成比例地增加,从而降低了乙醇的浓度。

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