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New analysis of the v2 band line intensities of the water molecule

机译:水分子的v2带谱线强度的新分析

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Abstract: New analysis is performed of a body of data on v$-2$/ band line intensities of the water molecule involving mainly the transitions reported by R. A. Toth. As a theoretical approach the formalism of the effective-dipole moment operators is used. We have been able to determine eight effective-dipole moment parameters, which result in a satisfactory agreement between observed and calculated intensities. The total RMS deviation of the fit is 6%.!7
机译:摘要:对水分子的v $ -2 $ /带线强度数据进行了新的分析,主要涉及R. A. Toth报告的跃迁。作为理论方法,使用了有效偶极矩算子的形式。我们已经能够确定八个有效偶极矩参数,这些参数在观察到的强度和计算的强度之间取得了令人满意的一致性。拟合的总RMS偏差为6%!! 7

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