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Vibration-rotational interaction and doublet structure of the 390-cm-1 quasi line in the fluorescence spectrum of anthracene vapors

机译:蒽蒸气荧光光谱中390-cm-1准线的振动-旋转相互作用和双峰结构

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Abstract: The report presents the results of the study of the intramolecular V-R Coriolis interaction between closely- spaced energy levels of a molecule with a certain symmetry of the wave functions corresponding to these levels using the anthracene molecule. As an example, the consideration of V-R interactions has been shown to result in the formation of doublet structure of the 390 cm$+$MIN@3$/ quasi-line in the emission spectrum.!16
机译:摘要:该报告介绍了使用蒽分子对分子的近距离能级之间的分子内V-R科里奥利相互作用的研究结果,该能级具有与这些能级相对应的波动函数。例如,V-R相互作用的考虑已显示出导致发射光谱中390 cm $ + $ MIN @ 3 $ /准线的双峰结构的形成!16

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