IR spectroscopy of interhalides XF3 and XF5 (X = Cl Br)

机译：卤化物XF3和XF5的红外光谱（X = Cl Br）

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Abstract: Interhalogens XF$-3$/ and XF$-5$/ (X $EQ Cl,Br) are widely used for reprocessing of nuclear materials, in electronic and iron-and-steel industries. At the same time XF$-3$/ and XF$-5$/ may be regarded among most dangerous components in the plumes of emergency ejections of these manufactures. The Cl and Br fluorides interact actively with atmospheric gases resulting in the formation of hydrogen halogen, Cl and Br oxyfluorides and oxides which are transformed into stable complexes (HHal)$-x$/...(H$-2$/O)$-y$/, where Hal $EQ F, Cl, Br; x $PLU y $GREQ 2. A study into reaction mechanisms with a participation of the XF$-3$/ and XF$-5$/ compounds, their secondary compounds and the applicability of the remote laser control techniques requires comprehensive information on vibration spectra of interhalogens.!30

机译：摘要：卤素间XF $ -3 $ /和XF $ -5 $ /（X $ EQ Cl，Br）被广泛用于电子和钢铁工业中的核材料后处理。同时，XF $ -3 $ /和XF $ -5 $ /可能被视为这些制造商紧急喷出烟气中最危险的部分。 Cl和Br的氟化物与大气中的气体相互作用活跃，从而形成卤化氢，Cl和Br的氟氧化物和氧化物，它们转变成稳定的络合物（HHal）$-x $ / ...（H $ -2 $ / O） $ -y $ /，其中Hal $ EQ F，Cl，Br； x $ PLU y $ GREQ 2.对于涉及XF $ -3 $ /和XF $ -5 $ /化合物，其次要化合物以及远程激光控制技术的适用性的反应机理的研究，需要有关振动的全面信息。卤素的光谱!! 30

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《13th Symposium and School on High-Resolution Molecular Spectroscopy》|1999年|p.166-171|共6页
会议地点 Tomsk(RU)
作者
Sh. S. Nabiev; Kurchatov Institute; Moscow; Russia.;
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中图分类物理学;
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IR spectroscopy of interhalides XF3 and XF5 (X = Cl Br)

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