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Spectral characteristics of 254-nm mercury line with consideration for hyperfine structure as a

机译:考虑超精细结构的254 nm汞谱线的光谱特性

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Abstract: The differential atomic absorption spectroscopy method is widely used both in scientific investigations and analytical applications. Absorption coefficient (absorption cross section) is an individual characteristics of every element therefore it provides for a high selectivity of an analysis. Differential absorption technique allows one to increase the selectivity by means of background absorption correction. In the cases where we should analyze gas mixtures at different pressures, we should take into account an influence of pressure on absorption line contour of the component to be analyzed. In the paper we present an estimation of such an influence. As an example, we consider an influence of pressure of analyzed gas mixture on sensitivity of RGA-11 differential atomic absorption analyzer with Zeeman background correction. This analyzer had been developed at Institute of Optical Monitoring SB RAS. The authors of the report are well experienced in its exploitation under different conditions.!8
机译:摘要:差分原子吸收光谱法已广泛用于科学研究和分析应用中。吸收系数(吸收截面)是每个元素的单独特征,因此它提供了很高的分析选择性。差分吸收技术允许通过背景吸收校正来提高选择性。在应分析不同压力下的混合气体的情况下,应考虑压力对待分析组分吸收线轮廓的影响。在本文中,我们提出了这种影响的估计。例如,我们考虑采用塞曼背景校正的分析气体混合物压力对RGA-11差分原子吸收分析仪灵敏度的影响。该分析仪是在SB RAS光学监测研究所开发的。该报告的作者在不同条件下的开发中经验丰富。!8

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