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首页> 外文会议>13th Symposium and School on High-Resolution Molecular Spectroscopy >Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions
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Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions

机译：振动相互作用联动排序理论中多原子分子的准简并振动态的有效四极耦合算子

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Abstract: The contribution have been devoted the construction of effective quadrupole coupling operator for quasidegenerate vibrational levels of polyatomic molecules and the reduction of the laser. The indeterminacy problem of the parameters in the effective vibrational-rotational H$+eff$/$-VR$/ and quadrupole W$-eff$/ Hamiltonians for the cases of accidental resonances linked with various groupings of vibrational- rotational interactions (problem of grouping uncertainty) are considered. The problem of the reduction of H$+eff$/ $EQ H$+eff$/$-VR$/ $PLU W$+eff$/ is discussed. The case of the Coriolis-type, accidental resonances have been considered more detail. New representation of H$+eff$/ $EQ H$+eff$/$- VR$/ $PLU W$+eff$/ for isolated vibration levels in form of angular moments only is presented.!8
机译：【摘要】该研究致力于构建有效的四极偶合算子，以实现多原子分子的准生成振动能级和激光的还原。对于与振动-旋转相互作用的各种分组相关的偶然共振的情况，有效振动-旋转H $ + eff $ / $-VR $ /和四极W $ -eff $ /哈密顿量中的参数不确定性问题分组不确定性）。讨论了减少H $ + eff $ / $ EQ H $ + eff $ / $-VR $ / $ PLU W $ + eff $ /的问题。对于科里奥利（Coriolis）型情况，意外共振已被认为更为详细。仅以角矩的形式给出了孤立振动水平的H $ + eff $ / $ EQ H $ + eff $ / $-VR $ / $ PLU W $ + eff $ /的新表示形式！8

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