HYDROGEN PEROXIDE DECOMPOSITION

机译：过氧化氢分解

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Environmental and toxicity concerns with hypergolic propellants have led to a resurgence of interest in hydrogen peroxide for various propellant applications. Major issues, however, with hydrogen peroxide are catalytic decomposition, materials compatibility and storage stability. The NASA Johnson Space Center White Sands Test Facility has developed techniques to monitor the decomposition of hydrogen peroxide over a range of temperatures. Using isothermal microcalorimetry we have measured decomposition rates showing the effects of temperature, materials of construction and stabilizer packages on the decomposition. In this presentation we detail the results of these studies and include an interlaboratory/intermethod comparison of measured rates of decomposition.

机译：对高推进剂的环境和毒性的关注已导致对用于各种推进剂应用的过氧化氢的兴趣重新出现。然而，过氧化氢的主要问题是催化分解，材料相容性和储存稳定性。美国宇航局约翰逊航天中心白沙试验设施已开发出可在一定温度范围内监测过氧化氢分解的技术。使用等温微量热法，我们测量了分解速率，显示出温度，结构材料和稳定剂包装对分解的影响。在本演示中，我们详细介绍了这些研究的结果，并包括了实验室间/方法间对测得的分解速率的比较。

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来源
《1st International conference on green propellant for space propulsion》|2001年|p.1-6|共6页
会议地点 Noordwijk(NL)
作者
Dennis D. Davis; Steven D. Hornung; David L. Baker;
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作者单位

Honeywell Technology Solutions Inc. NASA Johnson Space Center White Sands Test Facility Las Cruces, New Mexico;

rnHoneywell Technology Solutions Inc. NASA Johnson Space Center White Sands Test Facility Las Cruces, New Mexico;

rnNASA Johnson Space Center White Sands Test Facility Las Cruces, New Mexico;

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正文语种 eng
中图分类空气动力学;
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3. Decomposition and/or hydrogenation of hydrogen peroxide over Pd/Al2O3 catalyst in aqueous medium:Factors affecting the rate of H2O2 destruction in presence of hydrogen [J] . Vasant R.Choudhary, Chanchal Samanta, Prabhas Jana Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2007,第1期

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4. Yieldfactors for the formation of Oh radicals and hydrogen peroxide during the decomposition of aqueous ozone by pH-initiated chain reactions or by hydrogen peroxide or by uv irradiation [C] . Juerg Hoigne, Heinz Bader Ozone world congress . 1991

机译：通过pH引发的链式反应，过氧化氢或uv辐射在臭氧水溶液分解过程中形成Oh自由基和过氧化氢的屈服因子
5. Kinetics and mechanism of the catalysis of the decomposition of hydrogen peroxide by Schiff base complexes of copper(II). [D] . Beng, Timothy Kum. 2004

机译：铜的席夫碱配合物催化过氧化氢分解的动力学和机理。
6. Carbon dioxide mediates Mn(II)-catalyzed decomposition of hydrogen peroxide and peroxidation reactions [O] . Stefan I. Liochev, Irwin Fridovich 2004

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7. Carbon dioxide mediates Mn(II)-catalyzed decomposition of hydrogen peroxide and peroxidation reactions [O] . Liochev, Stefan I., Fridovich, Irwin 2004

机译：二氧化碳介导Mn（II）催化的过氧化氢分解和过氧化反应
8. Investigation on the Physics and Microfluidics of the Decomposition of Hydrogen Peroxide in MEMS Microthrusters. [R] . Tortora, P. 2017

机译：mEms微型超声波中过氧化氢分解的物理和微流体研究。

HYDROGEN PEROXIDE DECOMPOSITION

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