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Vibrational Modes of Oxygen Dimers in Germanium

机译:锗中氧二聚体的振动模式

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摘要

Infrared absorption of as-grown, heat-treated and electron irradiated Ge crystals enriched with either ~(16)O or ~(18)O oxygen isotopes has been studied. Vibrational absorption bands at 780, 818 and 857 cm~(-1) (741, 776 and 811 cm~(-1)) are assigned to di-oxygen complexes (dimers) in Ge:~(16)O (~(18)O). This assignment is based on an analysis of positions and isotopic shifts of the lines as well as on an investigation of dependencies of line intensities on heat-treatment temperature and oxygen content in the crystals. It is argued that there are two configurations of oxygen dimers in Ge, the bands at 780 and 818 cm~(-1) being related to one of them and the band at 857 cm~(-1) to another. The binding energy of the dimer giving rise to the bands at 780 and 818 cm~(-1) is estimated to be about 0.35-0.4 eV.
机译:研究了生长中,经过热处理和电子辐照的富含〜(16)O或〜(18)O氧同位素的Ge晶体的红外吸收。在780、818和857 cm〜(-1)(741、776和811 cm〜(-1))处的振动吸收带被分配给Ge:〜(16)O(〜(18 )O)。这种分配是基于对谱线的位置和同位素位移的分析,以及对谱线强度对晶体中热处理温度和氧含量的依存关系的研究。有人认为,Ge中的氧二聚体有两种构型,分别在780和818 cm〜(-1)处的谱带与其中一个有关,而在857 cm〜(-1)处的谱带与另一种有关。产生在780和818cm-1(-1)处的带的二聚体的结合能估计为约0.35-0.4eV。

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