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Materials for Mediator-free Electron Transfer in the Enzymatic Electrodes of Biobatteries and Biofuel Cells

机译:生物电池和生物燃料电池酶电极中无介体电子转移的材料

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摘要

We present functionalization of single-walled carbon nanotubes (SWCNTs) and their application in the enzymatic fuel cells construction. SWCNTs were covalently modified with different types of aromatic moieties. Free radical reaction was employed to create direct carbon-carbon bond between moiety and SWCNTs. In second approach functionalization takes place through amide bonding. Functionalized SWCNTs were characterized by spectroscopy and by thermogravimetric analysis. Experimental measurements confirmed usability of the new materials for construction of bioelectrodes for enzymatic fuel cells.
机译:我们目前功能的单壁碳纳米管(SWCNTs)及其在酶燃料电池中的应用。 SWCNT被不同类型的芳族部分共价修饰。自由基反应用于在部分和SWCNT之间建立直接的碳碳键。在第二种方法中,官能化通过酰胺键进行。通过光谱学和热重分析来表征功能化的SWCNT。实验测量证实了用于酶燃料电池生物电极的新材料的可用性。

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  • 来源
    《Biological fuel cells 5》|2012年|1-8|共8页
  • 会议地点 SeattleWA(US)
  • 作者单位

    Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Narutowicza St. 11-12,80-233 Gdansk, Poland;

    Faculty of Chemistry, Warsaw University, Pasteura St. 1, 02-093 Warsaw, Poland;

    Faculty of Chemistry, Warsaw University, Pasteura St. 1, 02-093 Warsaw, Poland;

    Chemical Faculty, Gdansk University of Technology, Narutowicza St. 11-12,80-233 Gdansk, Poland;

    Department of Biochemistry, Maria Curie Sklodowska University, Akademicka 19, 20-031 Lublin, Poland;

    Faculty of Chemistry, Warsaw University, Pasteura St. 1, 02-093 Warsaw, Poland;

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  • 正文语种 eng
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