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Single-Walled Carbon Nanotubes / Polymer Nanocomposites Microbeams by Means of Ultraviolet-Assisted Direct-Write Assembly

机译:单壁碳纳米管/聚合物纳米复合材料通过紫外线辅助直接写入组装

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We report the successful fabrication of nanocomposite microbeams by means of ultraviolet-assisted direct-write assembly. The nanocomposite consists of a UV curable resin reinforced by single-walled carbon nanotubes (C-SWNTs). The C-SWNTs were produced by the UV-laser ablation method, physico-chemically purified and dispersed in the polymer matrix using sonication in dichloromethane. The as-grown and purified C-SWNTs were systematically characterized by microRaman and photoelectron spectroscopy. Carboxyl groups were attached to the C-SWNT during the purification procedure. Eight different nanocomposite blends were produced from as-grown and purified C-SWNT at varying concentrations. The UV-assisted direct-write approach consists of the robotically-controlled micro-extrusion of the C-SWNT/polymer nanocomposite under UV exposure. Cylindrical microbeams were deposited in a layer-by-layer mode and in a freeform fabrication fashion in order to achieve a mechanical testing micro-coupon. A comprehensive study under dynamic mechanical analyzer was performed on microrods (diameter (d) of ~200 μm) spanning a distance (L) of 3 mm for an aspect ratio (L/d) of 15. An increase by ~63% in strength and ~47% in modulus is measured for the microbeams using the 0,6wt% purified C-SWNT reinforcement.
机译:我们报告通过紫外线辅助直接写入大会成功制作纳米复合微束。纳米复合材料由单壁碳纳米管(C-SWNT)增强的紫外线固化树脂组成。 C-SWNTs是通过UV激光烧蚀法生产的,经过物理化学纯化,并使用二氯甲烷进行超声处理分散在聚合物基质中。通过显微拉曼光谱和光电子能谱系统地表征了生长和纯化的C-SWNT。在纯化过程中,羧基连接到C-SWNT上。从生长和纯化后的C-SWNT以不同浓度生产八种不同的纳米复合混合物。紫外线辅助直接写入方法包括在紫外线照射下自动控制C-SWNT /聚合物纳米复合材料的微挤出。圆柱形微束以逐层模式和自由形式的制造方式沉积,以实现机械测试的微型优惠券。在动态力学分析仪上对跨度为3的距离(L)为15的长径比(L / d)的微棒(直径(d)〜200μm)进行了全面研究。强度增加了〜63%使用0.6%(重量)的纯C-SWNT增强材料测得的微束的模量约为47%。

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