首页> 外文会议>International symposium on halogenated persistent organic pollutants >ANTHROPOGENIC AND NATURALLY-PRODUCED ORGANOBROMINATED COMPOUNDS IN BLUEFIN TUNA FROM THE MEDITERRANEAN SEA
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ANTHROPOGENIC AND NATURALLY-PRODUCED ORGANOBROMINATED COMPOUNDS IN BLUEFIN TUNA FROM THE MEDITERRANEAN SEA

机译:地中海海蓝鳍金枪鱼的人为和自然产生的有机溴化化合物

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摘要

Anthropogenic compounds, such as polybrominated diphenyl ethers (PBDEs), together with naturally-produced organobromines, such as methoxylated PBDEs (MeO-PBDEs), polybrominated hexahydroxanthene derivates (PBHDs), 2,4,6-tribromoanisole (TBA) and a mixed halogenated monoterpene (MHC-1), were measured in muscle from 26 farmed and wild bluefin tuna (Thunnus thynnus) caught in the Mediterranean Sea. This species is ecological attractive because of the changes of geographic habitat throughout its long lifespan which affect its feeding and because it is a part of human diet (especially for people living on coastal areas). PBDE concentrations were similar between tuna samples of different groups (17-149 ng/g lw in farmed tuna, 25-219 ng/g lw in longline-fished tuna and 26-126 ng/g lw in net-fished tuna). However, higher concentrations of naturally-produced MeO-PBDEs and PBHDs were observed in the two types of wild tuna (longline-fished and net-fished) compared to farmed tuna suggesting that wild tunas come easily in contact with sources of these compounds. In all cases, PBHDs presented the highest contribution to the sum of organobromines (50% in farmed tuna and > 90% in wild tuna). TBA was detected at low concentrations (< 6 ng/g lw), while MHC-1 was found at higher levels (up to 42 ng/g lw) in farmed tuna. The estimated daily ingestion of PBDEs from tuna was 830 ng PBDEs/day, regardless of the origin of the tuna. While this value is approximately 600 times lower that the minimum risk level set by the U.S. Department of Health and Human Services, it is approximately 8 times higher than the total intake of PBDEs via diet, suggesting that consumption of tuna can add considerably to the total daily intake of PBDEs.
机译:人为化合物,例如多溴联苯醚(PBDEs),以及天然产生的有机溴,例如甲氧基化PBDEs(MeO-PBDEs),多溴化六氢氧杂蒽衍生物(PBHD),2,4,6-三溴苯甲醚(TBA)和混合卤代在地中海捕捞的26种养殖和野生蓝鳍金枪鱼(Thunnus thynnus)的肌肉中测量了单萜(MHC-1)。该物种具有生态吸引力,因为其整个寿命范围内的地理栖息地变化都会影响其觅食,而且它是人类饮食的一部分(尤其是对于沿海地区的人们而言)。不同组金枪鱼样品之间的PBDE浓度相似(养殖金枪鱼为17-149 ng / g lw,延绳钓金枪鱼为25-219 ng / g lw和网捕金枪鱼为26-126 ng / g lw)。但是,与养殖金枪鱼相比,在两种类型的野生金枪鱼(延绳钓和网捕)中观察到更高浓度的天然产生的MeO-PBDEs和PBHDs,这表明野生金枪鱼很容易与这些化合物的来源接触。在所有情况下,PBHD对有机溴的总含量贡献最大(在养殖金枪鱼中占50%,在野生金枪鱼中占90%以上)。在养殖金枪鱼中,TBA的浓度低(<6 ng / g lw),而MHC-1的含量较高(最高42 ng / g lw)。无论金枪鱼的来源如何,估计每天从金枪鱼摄入的多溴二苯醚的摄入量为每天830 ng PBDEs。尽管该值比美国卫生与公共服务部设定的最低风险水平低约600倍,但比通过饮食摄入的多溴二苯醚的总摄入量高约8倍,这表明金枪鱼的食用量可大大增加总摄入量。每天摄入多溴二苯醚。

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  • 会议地点 Beijing(CN)
  • 作者单位

    Department of Instrumental Analysis and Environmental Chemistry,IQOG (CSIC),Juan de la Cierva 3,28006 Madrid,Spain;

    Toxicological Center,Department of Pharmaceutical Sciences,University of Antwerp,Universiteitsplein 1,2610 Wilrijk,Belgium Laboratory for Ecophysiology,Biochemistry and Toxicology,Department of Biology,University of Antwerp,Groenenborgerlaan 171,2020 Antw;

    Department of Instrumental Analysis and Environmental Chemistry,IQOG (CSIC),Juan de la Cierva 3,28006 Madrid,Spain;

    G. Sarfatti Department of Environmental Sciences,University of Siena,via P.A. Mattioli,4,53100 Siena,Italy;

    G. Sarfatti Department of Environmental Sciences, University of Siena, via P.A. Mattioli, 4, 53100 Siena, Italy;

    Toxicological Center, Department of Pharmaceutical Sciences, University of Antwerp, Universitei;

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  • 正文语种 eng
  • 中图分类 环境分析化学;
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