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Co~(2+) ions-containing ordered silica monoliths: Influence of the copolymer P123/Si and Co~(2+) ions/Si ratios on the organization of the monoliths

机译:含Co〜(2+)离子的有序二氧化硅整体结构:共聚物P123 / Si和Co〜(2+)离子/ Si的比例对整体结构的影响

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摘要

Among the different possibilities to control the size, the shape and the spatial organization of nano-objects, one consists in the use of the ordered mesoporosity of silica matrices as nanoreactors for their synthesis. This strategy has been used to elaborate Prussian Blue Analogues (PBA) exhibiting photomagnetic properties. Since the synthesis of these nanocomposites begins with the obtention of mesoporous silica monoliths containing Co~(2+) ions, we focus in this paper on the effect of the quantity of Co~(2+) ions and the amount of surfactant on the nanostructuration of these monoliths.
机译:在控制纳米物体的尺寸,形状和空间组织的不同可能性中,一种方法是使用有序介孔的二氧化硅基质作为纳米反应器进行合成。该策略已被用于阐述展示光磁特性的普鲁士蓝类似物(PBA)。由于这些纳米复合材料的合成始于获得含有Co〜(2+)离子的介孔二氧化硅整体结构,因此本文重点研究Co〜(2+)离子的量和表面活性剂的量对纳米结构的影响。这些巨石。

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