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PROPERTY IMPROVEMENT OF MOCVD-PZT FILMS DEPOSITED BELOW 400℃

机译:沉积温度低于400℃的MOCVD-PZT薄膜的性能改进

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RuO_2/(200-nm thick PZT)/RuO_2 capacitors were prepared by MOCVD. RuO_2 and PZT films were prepared at 350, and 395 and 445℃ from DER - O_2 and Pb(C_(11)H_(19)O_2)_2 - Zr(O· t-C_4H_9)_4 - Ti(O · i-C_3H_7)_4 - O_2 systems, respectively. Clear hysteresis loops originated to ferroelectricity was observed for the PZT films deposited at 445℃ but was not at 395℃. However, by the addition of 10-nm thick Pt layer prepared on the RuO_2 bottom electrode by e-beam evaporation, ferroelectricity above 30 μC/cm~2 in remanent polarization (P_r) was obtained for the PZT films deposited at 395℃. This shows that the existence of Pt layer improved the crystallinity of PZT phase. This capacitor shows hardly fatigue up to 1 x 10~(10) switching cycles, suggesting the fatigue free characteristics.
机译:通过MOCVD制备RuO_2 /(200nm厚的PZT)/ RuO_2电容器。从DER-O_2和Pb(C_(11_H_(19)O_2)_2-Zr(O·t-C_4H_9)_4-Ti(O·i-C_3H_7)分别在350、395和445℃制备RuO_2和PZT薄膜)_4-分别为O_2系统。在445℃沉积的PZT薄膜观察到明显的铁电磁滞回线,而在395℃则没有。然而,通过在电子束蒸发上在RuO_2底部电极上制备10 nm厚的Pt层,在395℃下沉积的PZT膜获得了剩余极化(P_r)大于30μC/ cm〜2的铁电。这表明Pt层的存在改善了PZT相的结晶度。该电容器在1 x 10〜(10)的开关周期内几乎没有疲劳,这表明它没有疲劳特性。

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