Organic anion intercalation in layered double hydroxides

机译：有机阴离子在层状双氢氧化物中的嵌入

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The synthesis of several types of organic intercalates of Mg-Al layered double hydroxides are described. The materials are made by co-precipitation. Anions considered are benzoate, benzenesulphonate and phenylphosphonate. The crystallinity of the products depends on the MG/Al ratio within the hydroxide layer. At high Mg/Al values competition with nitrate anions during synthesis inhibits incorporation of the organic anion. In competitive uptake experiments the doubly charged phosphonate anion dominates.

机译：描述了几种类型的Mg-Al层状双氢氧化物有机插层的合成。该材料是通过共沉淀制备的。认为的阴离子是苯甲酸酯，苯磺酸酯和苯膦酸酯。产物的结晶度取决于氢氧化物层内的MG / Al比。在高Mg / Al值下，在合成过程中与硝酸根阴离子的竞争会抑制有机阴离子的掺入。在竞争性吸收实验中，双电荷的膦酸根阴离子占主导地位。

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来源
《Fifth International Conference on Ion Exchange Processes held on 5-9 July 1998 at Plas Coch College, The North East Wales Institute, Wrexham, UK》|1998年|p.166-175|共10页
会议地点 Wrexham(GB)
作者
Sylvie Bonnet; William Jones;
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正文语种 eng
中图分类化学工业;
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Organic anion intercalation in layered double hydroxides

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