STABILITY IMPROVEMENT OF SOLID-STATE DYE-SENSITIZED PHOTOVOLTAIC CELL BY ADDING IMIDAZOLIUM THIOCYANATE TO COPPER IODIDE p-TYPE SEMICONDUCTOR LAYER

机译：通过将硫氰酸咪唑酯添加到碘化铜p型半导体层上来提高固态染料敏化的光伏电池的稳定性

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The difficulty of fabricating dye-sensitized solid-state solar cells with p-CuI deposited from acetoinitile solution has been the problem of filling the pores of the dyed nanocrystalline TiO_2 film with the CuI crystallites. It is found that incorporation of a small quantity of the molten salt 1-methyl-3-ethylimidazolium thiocyanate to the CuI solution helps filling of the pores greatly improving the performance of the cell. This imidazolium salt acts as a CuI crystal growth inhibitor and being a molten salt the residue formed during evaporation of the solvent spreads over the crystallite grain boundaries. The mechanism of crystal growth inhibition by 1-methyl-3-ethylimidazolium thiocyanate and its action in facilitating hole transport across the grain boundaries are explained.

机译：用从丙酮溶液沉积的p-CuI来制造染料敏化的固态太阳能电池的困难一直是用CuI微晶填充染色的纳米晶TiO_2膜的孔的问题。发现将少量的熔融盐1-甲基-3-乙基咪唑硫氰酸盐熔融盐加入CuI溶液中有助于填充孔，从而极大地改善了电池的性能。该咪唑鎓盐用作CuI晶体生长抑制剂，并且是熔融盐，在溶剂蒸发期间形成的残留物散布在微晶界上。解释了1-甲基-3-乙基咪唑硫氰酸盐对晶体生长的抑制作用及其在促进空穴跨晶界传输方面的作用。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.124-127|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Akinori Konno; G. R. Asoka Kumara; Kirthi Tennakone;
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Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Hamamatsu, 432-8561 Japan;

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正文语种 eng
中图分类化学;
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1. Dye-Sensitized Solid-State Photovoltaic Cells Based on Dye Multilayer-Semiconductor Nanostructures [J] . V. P. S. Perera, P. K. D. D. P. Pitigala, P. V. V. Jayaweera, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2003,第50期

机译：基于染料多层半导体纳米结构的染料敏化固态光伏电池
2. Lithium salts as 'redox active' p-type dopants for organic semiconductors and their impact in solid-state dye-sensitized solar cells [J] . Antonio Abate, Tomas Leijtens, Sandeep Pathak Physical chemistry chemical physics: PCCP . 2013,第7期

机译：锂盐作为有机半导体的“氧化还原活性” p型掺杂剂及其对固态染料敏化太阳能电池的影响
3. Tris(2-(1H-pyrazol-1-yl)pyridine)cobalt(lll) as p-Type Dopant for Organic Semiconductors and Its Application in Highly Efficient Solid-State Dye-Sensitized Solar Cells [J] . Julian Burschka, Amalie Dualeh, Florian Kessler, Journal of the American Chemical Society . 2011,第45期

机译：作为有机半导体的p型掺杂剂的Tris（2-（1H-吡唑-1-基）吡啶）钴（III）及其在高效固态染料敏化太阳能电池中的应用
4. Stability improvement of solid-state dye-sensitized photovoltaic cell by adding imidazolium thiocyanate to copper iodide p-type semiconductor layer [C] . Akinori Konno, G. R. Asoka Kumara, Kirthi tennakone International Manuel M. Baizer Symposium . 2002

机译：通过将硫代吡啶亚氰酸亚氰酸亚硫代吡啶吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡吡酸铜稳定性改进
5. STUDIES IN SOLID-STATE PHYSICS: ONE: CRITICAL EFFECTS IN DYSPROSIUM AND RUBIDIUM-SILVER-IODIDE, TWO: ELECTROABSORPTION BY LAYERED SEMICONDUCTORS. [D] . LEDERMAN, FRANK LOUIS -1

机译：固态物理学的研究：一：AND和碘化R-碘化银的临界效应，二：层状半导体的电吸附。
6. Assessing the suitability of copper thiocyanate as a hole-transport layer in inverted CsSnI3 perovskite photovoltaics [O] . Anjana Wijesekara, Silvia Varagnolo, G. Dinesha M. R. Dabera, -1

机译：评估硫氰酸铜在倒CsSnI3钙钛矿光伏电池中作为空穴传输层的适用性
7. Effect of Imidazolium Salts on the Performance of Solid-state Dye-sensitized Photovoltaic Cell Using Copper Iodide as a Hole Collector [O] . Akinori KONNO, Gamaralalage R.A. KUMARA, Ryosuke HATA, 2002

机译：咪唑鎓盐对使用铜碘化铜作为孔收集器的固态染料光伏电池性能的影响

STABILITY IMPROVEMENT OF SOLID-STATE DYE-SENSITIZED PHOTOVOLTAIC CELL BY ADDING IMIDAZOLIUM THIOCYANATE TO COPPER IODIDE p-TYPE SEMICONDUCTOR LAYER

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