REDUCTION OF ALKYL HALIDES BY ELECTROGENERATED COBALT(Ⅰ) SALEN AND NICKEL(Ⅰ) SALEN: REACTIONS OF ALKYL RADICALS WITH NO AND O_2

机译：电生钴（Ⅰ）盐和镍（Ⅰ）盐的还原卤代烷：烷基自由基与NO和O_2的反应。

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Cobalt(Ⅰ) salen, electrogenerated in DMF containing 0.10 M TMABF_4, oxidatively adds to (2-bromoethyl)benzene to form (2-phenyl-ethyl)cobalt(Ⅲ) saten, which undergoes photolysis to afford the 2-phenylethyl radical and cobalt(Ⅱ) salen. In the presence of nitric oxide, the alkyl radical reacts to give an oxime and a nitrile. When an alkyl halide (1-bromooctane) is introduced into a solution of electrogenerated nickel(Ⅰ) salen in DMF-0.10 M TMABF_4 containing added water, followed by exposure of the mixture both to ultraviolet-visible light and to air (or oxygen), the corresponding aldehyde (octanal) can be obtained in a yield of up to 74%.

机译：在含0.10 M TMABF_4的DMF中电生成的钴（Ⅰ）塞伦，氧化添加到（2-溴乙基）苯中形成（2-苯基乙基）钴（Ⅲ）饱和碳酸钠，对其进行光解得到2-苯基乙基和钴（Ⅱ）塞伦。在一氧化氮的存在下，烷基自由基反应生成肟和腈。将卤代烷（1-溴辛烷）引入DMF-0.10 M TMABF_4中的水生成的镍镍（Ⅰ）溶液中，然后将混合物暴露于紫外可见光和空气（或氧气）中，可以以高达74％的产率获得相应的醛（辛醛）。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.100-103|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Dennis G. Peters; Chang Ji; Benjamin J. Wozniak; Parichatr Vanalabhpatana;
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Department of Chemistry, Indiana University, Bloomington, IN 47405 (U.S.A.);

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正文语种 eng
中图分类化学;
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1. Electrochemistry of substituted salen complexes of nickel(II): Nickel(I)-catalyzed reduction of alkyl and acetylenic halides [J] . Matthew P. Foley, Peng Du, Kent J. Griffith, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2010,第2期

机译：镍（II）的取代Salen配合物的电化学：镍（I）催化还原烷基卤化物和炔属卤化物
2. Stoichiometric reduction of secondary alkyl monohalides by electrogenerated nickel(I) salen in the presence of oxygen and water: Prospects for the formation of ketones [J] . Vanalabhpatana P, Peters DG Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2006,第1a2期

机译：在氧气和水存在下通过电生镍（I）沙伦化学计量还原仲烷基单卤化物：酮形成的前景
3. Stoichiometric reduction of primary alkyl monohalides with electrogenerated nickel(I) salen: Formation of aldehydes [J] . Vanalabhpatana P, Peters DG, Karty JA Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2005,第2期

机译：电生镍（I）的化学计量还原伯烷基一卤化物：醛的形成
4. Reduction of alkyl halides by electrogenerated cobalt(I) salen and nickel(I) salen: reactions of alkyl radicals with no and O_2 [C] . Dennis G. Peters, Chang Ji, Benjamin J. Wozniak, International Manuel M. Baizer Symposium . 2002

机译：通过电子化钴（I）盐和镍（I）盐来减少烷基卤化物：烷基的反应没有NO和O_2
5. Development of a chemical means to mimic nucleo-cytoplasmic transport and catalytic reduction of secondary alkyl monohalides by cobalt(I) salen and nickel(I) salen electrogenerated at vitreous carbon electrodes. [D] . Bird, Sean Patrick. 2016

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机译：烷基自由基对烷基卤化物的快速卤素提取。使用烷基卤化物机械探针进行研究的过程的定量和研究注意事项

REDUCTION OF ALKYL HALIDES BY ELECTROGENERATED COBALT(Ⅰ) SALEN AND NICKEL(Ⅰ) SALEN: REACTIONS OF ALKYL RADICALS WITH NO AND O_2

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