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首页> 外文会议>Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA >New Methodologies for Preparation of Highly-Regulated Structure Films of Conducting Polymers
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New Methodologies for Preparation of Highly-Regulated Structure Films of Conducting Polymers

机译：制备导电聚合物高调控结构膜的新方法

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We succeeded in preparing three-dimensionally dense films of polyaniline, polythiophene and polypyrrole by the electrooxidative polymerization of the corresponding aromatic monomers under ultrasonic irradiation with a power higher than the cavitation threshould. On the other hand, centrifugal effects on the electrochemical polymerization of aniline, thiophene and pyrrole were examined under a centrifugal acceleration force of 1 to 300 g. The polymerization rate, chemical and physical properties and morphological structure of the films were greatly affected by the cetrifugal field. In addition, it was found that the use of the ionic liquid as an electrolyte could not only regulate the morphological structure but also increase the electrochemical capacity density and electroconductivity of polypyrrole and polythiophene films.
机译：我们通过相应的芳族单体在超声辐射下以高于空化强度的功率进行电氧化聚合，成功制备了聚苯胺，聚噻吩和聚吡咯的三维致密膜。另一方面，在1〜300g的离心加速力下，研究了对苯胺，噻吩和吡咯的电化学聚合的离心作用。薄膜的聚合速率，化学和物理性能以及形态结构都受到盲肠场的影响。另外，发现使用离子液体作为电解质不仅可以调节形态结构，而且可以提高聚吡咯和聚噻吩膜的电化学容量密度和导电性。

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