Electrochemical Carbonylation of Primary Amines to Symmetrical N,N'-Disubstituted Ureas Using Palladium (Ⅱ) Catalyst in Combination with its Anodic Recycling

机译：钯（Ⅱ）与阳极再循环相结合将伯胺电化学羰基化为对称的N，N'-二取代尿素

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A new procedure for an efficient synthesis of N,N'-disubstituted ureas was developed. Aromatic and aliphatic primary amines undergo oxidative carbonylation under atmospheric pressure of carbon monoxide, using Pd(Ⅱ) catalyst in combination with its anodic recycling at a graphite electrode.

机译：开发了一种有效合成N，N'-二取代脲的新方法。芳香族和脂肪族伯胺在Pd（Ⅱ）催化剂及其在石墨电极上的阳极循环作用下，在一氧化碳的大气压下进行羰基氧化。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.33-35|共3页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Isabella Chiarotto; Marta Fcroci;
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Universita degli Studi "La Sapienza". Dipartimento di Ingegneria Chimica dei Materiali delle Materie Prime e Melallurgia via Castro Laurenziano, 71-00161 Rome, Italy;

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正文语种 eng
中图分类化学;
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专利

1. A novel ZrO_2-SO_4~(2-) supported palladium catalyst for syntheses of disubstituted ureas from amines by oxidative carbonylation [J] . Feng Shi, Youquan Deng, Tianolong SiMa, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第11期

机译：一种新型的ZrO_2-SO_4〜（2-）负载型钯催化剂，通过氧化羰基化反应由胺合成双取代的脲
2. Palladium-catalyzed synthesis of symmetrical urea derivatives by oxidative carbonylation of primary amines in carbon dioxide medium [J] . Ca N.D., Bottarelli P., Dibenedetto A., Journal of Catalysis . 2011,第1期

机译：钯介质中伯胺的氧化羰基化反应钯催化合成对称脲衍生物
3. N-heterocyclic carbene-palladium complexes as efficient catalysts for the oxidative carbonylation of Amines to ureas [J] . Zheng SZ, Peng XG, Liu JM, Helvetica chimica acta . 2007,第8期

机译：N-杂环卡宾-钯配合物可作为胺氧化羰基化为脲的有效催化剂
4. Electrochemical Carbonylation of Primary Amines to Symmetrical N, N'-Disubstituted Ureas Using Palladium (II) Catalyst in Combination with its Anodic Recycling [C] . Isabella Chiarotto, Marta Feroci International Manuel M. Baizer Symposium . 2002

机译：使用钯（II）催化剂与其阳极回收相结合的初级胺的电化学羰基化对对称的N，N'-二取代脲
5. Catalytic oxidative carbonylation of amino alcohols and diamines to ureas as an alternative to phosgene derivatives: Synthesis of disubstituted hydantoins. [D] . Diaz-Monterroso, Delmy. 2007

机译：氨基醇和二胺催化氧化羰基化为脲，替代光气衍生物：二取代乙内酰脲的合成。
6. Cyclization-Carbonylation-Cyclization Coupling Reaction of Propargyl Ureas with Palladium(II)-Bisoxazoline Catalyst [O] . Taichi Kusakabe, Koujiro Kawaguchi, Miya Kawamura, 2012

机译：炔丙基脲与钯（II）-双异恶唑啉催化剂的环-羰基化-环偶联反应
7. Mono- and double carbonylation of aryl iodides with amine nucleophiles in the presence of recyclable palladium catalysts immobilised on a supported dicationic ionic liquid phase [O] . Papp M., Szabó P., Srankó D., 2017

机译：在固定在负载型阳离子型离子液体液相上的可回收钯催化剂存在下，芳基碘化物与胺亲核试剂的单羰基和双羰基化

Electrochemical Carbonylation of Primary Amines to Symmetrical N,N'-Disubstituted Ureas Using Palladium (Ⅱ) Catalyst in Combination with its Anodic Recycling

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