N-OXYL-MEDIATED ELECTROOXIDATION OF ALCOHOLS IN SILICA GEL-AQUEOUS NaOCl DISPERSE SYSTEMS (EX-CELL METHOD). A COLUMN-FLOW SYSTEM

机译：N-氧羰基介导的氧化硅在硅胶凝胶水分散体系中的醇（EX-CELL方法）。柱流系统

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N-Oxyl-mediated oxidation of alcohols was performed successfully in a disperse system with N-oxyl-immobilized silica gel as a disperse phase and aqueous NaOCl as a disperse media. Column-flow systems were also investigate as a new device for automated oxidation process; thus, simple operations, e. g., 1) adsorption of alcohol in the silica gel column, 2) treatment with aqueous NaOCl, 3) extraction with acetone, 4) evaporation of the solvents afforded the corresponding ketone in good yields.

机译：在固定有N-氧基的硅胶为分散相，以NaOCl水溶液为分散介质的分散体系中，成功地进行了N-氧羰基介导的醇氧化反应。还研究了柱流系统作为自动氧化过程的新设备。因此，简单的操作，例如。例如，1）在硅胶柱上吸附醇，2）用NaOCl水溶液处理，3）用丙酮萃取，4）蒸发溶剂，得到相应的酮，收率很高。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.21-24|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Hideo Tanaka; Machiko Mine; Akimi Morimoto; Jingyu Chou; Manabu Kuroboshi;
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Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-Naka, Okayama, 700-8530, Japan;

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原文格式 PDF
正文语种 eng
中图分类化学;
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1. Electrooxidation of Alcohols in N-Oxyl-Immobilized Silica Gel/Water Disperse System: Approach to Totally Closed System [J] . Manabu Kuroboshi, Kentaro Goto, Hideo Tanaka Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2009,第6期

机译：N-羟基固定化硅胶/水分散体系中醇的电氧化：全封闭体系的方法
2. Electrooxidation of Alcohols in iV-Oxyl-Immobilized Silica Gel/Water Disperse System: Approach to Totally Closed System [J] . Manabu Kuroboshi, Kentaro Goto, Hideo Tanaka Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2009,第6期

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3. An aqueous silica gel disperse electrolysis system.N-Oxyl-mediated electrooxidation of alcohols [J] . Hideo Tanaka, Yusuke Kawakami, Kentaro Goto, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第3期

机译：水性硅胶分散电解系统，N-氧羰基介导的醇的电氧化
4. N-Oxyl-mediated electrooxidation of alcohols in silica gel-aqueous NaOCl disperse systems (ex-cell method). a column-flow system [C] . Hideo Tanaka, Machiko Mine, Akimi Morimoto, International Manuel M. Baizer Symposium . 2002

机译：N-氧基介导的硅胶水溶液分散系统中醇的电氧化（离细胞法）。列流系统
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N-OXYL-MEDIATED ELECTROOXIDATION OF ALCOHOLS IN SILICA GEL-AQUEOUS NaOCl DISPERSE SYSTEMS (EX-CELL METHOD). A COLUMN-FLOW SYSTEM

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