LITHIUM ACTIVITIES IN LITHIUM TRANSITION METAL DOUBLE OXIDE

机译：锂过渡金属双氧化物中的锂活性

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Lithium activity at equilibrium between LiCoO_2 and Co_3O_4, Fe_2O_3 and LiFe_5O_8, LiFe_5O_8 and LiFeO_2, Cr_2O_3 and LiCrO_2, and Mn_2O_3 and LiMn_2O_4 were measured using a solid state electrochemical cell with Li ion conducting glass-ceramics electrolyte at high temperatures. The standard Gibbs free energies of formation of lithium transition metal double oxides, LiCoO_2, LiFe_5O_8, LiFeO_2, LiCrO_2, LiMn_2O_4, were determined from the measured Lithium activities.

机译：使用具有Li离子传导性玻璃陶瓷电解质的固态电化学电池，在高温下测量LiCoO_2和Co_3O_4，Fe_2O_3和LiFe_5O_8，LiFe_5O_8和LiFeO_2，Cr_2O_3和LiCrO_2，以及Mn_2O_3和LiMn_2O_4之间处于平衡状态的锂活性。由测得的锂活性确定了形成锂过渡金属双氧化物LiCoO_2，LiFe_5O_8，LiFeO_2，LiCrO_2，LiMn_2O_4的标准吉布斯自由能。

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《Fourth International Symposium on Ionic and Mixed Conducting Ceramics, null》||p.272-279|共8页
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Kenichi Kawamura; Koji Asano; Shirou Nagano; Atsushi Kaimai; Keiji Yashiro; Yutaka Nigara; Tatsuya Kawada; Junichiro Mizusaki;
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Department of Metallurgy and Ceramics Science, Graduate School of Science and Engineering, Tokyo Institute of Technology 2-12-1 Ookayama, Meguro-ku, Tokyo 152―8552, JAPAN;

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LITHIUM ACTIVITIES IN LITHIUM TRANSITION METAL DOUBLE OXIDE

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