Electron Transfer Reduction of Fluorofullerenes, C_(60)F_(18) and C_3 C_(60)F_(36)

机译：氟富勒烯，C_（60）F_（18）和C_3 C_（60）F_（36）的电子转移还原

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Election transfer reduction of fluorofullerenes, C_(60)F_(36) and C_(60)F_(18) occurs efficiently to yield the defluorinated anion, C_(60)F_(35~-) and C_(60)F_(17~-) respectively. Defluorinated products are detected by negative-ion clectiospray ionization (ESI) mass spectroscopy. Dynamics of the defluorination was monitored by ESR and UV-visible spectra at low temperatures. The radical anions of fluorofullerenes are detected by ESR spectroscopy in the photo-induced electron transfer from dimeric 1-benzyl-1,4-dihy dronicotinamide to the fluorofullerenes. The one-electron reduction potential of C_(60)F_(18) is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron transfer from 10,10'-dimethyl-9,9',10,10'-tetrahydro-9,9'-biacridine to C_(60)F_(18) with those of other one-electron reductants.

机译：氟富勒烯C_（60）F_（36）和C_（60）F_（18）的选择转移还原有效地发生，以产生脱氟阴离子C_（60）F_（35〜-）和C_（60）F_（17〜 -）分别。通过负离子电喷雾电离（ESI）质谱法检测脱氟产物。在低温下，通过ESR和紫外可见光谱监测脱氟的动力学。氟富勒烯的自由基阴离子是通过ESR光谱在从二聚1-苄基-1,4-二氢十二碳二酰胺到氟富勒烯的光诱导电子转移中检测的。通过比较从10,10'-二甲基-9,9'，10,10转移电子的速率常数，将C_（60）F_（18）的单电子还原电位评估为0.04 V（vs. SCE） '-tetrahydro-9,9'-biacridine与其他单电子还原剂反应生成C_（60）F_（18）。

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《Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices: Fullorenes》|2003年|P.20-30|共11页
会议地点 Paris(FR);Paris(FR);Paris(FR)
作者
Kei Ohkubo; Roger Taylor; Olga V. Boltalina; Shunichi Fukuzumi;
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Department of Mate rial and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation, Suita, Osaka 565-0871, Japan;

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正文语种 eng
中图分类无机高分子化合物（高聚物）;
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1. In the first proven S_N2′ fullerene reaction, both C_3 and C_1 C_(60)F_(36) hydrolyse to C_1 isomers of C_(60)F_(35)OH that eliminate HF to give epoxides C_(60)F_(34)O; C_(60)F_(36)O oxides are shown to be ethers, and a fourth isomer of C_(60)F_(36) exi [J] . Anthony G. Avent, Alaa K. Abdul-Sada, Brian W. Clare, Organic & biomolecular chemistry . 2003,第6期

机译：在第一个证明的S_N2'富勒烯反应中，C_3和C_1 C_（60）F_（36）均水解为C_（60）F_（35）OH的C_1异构体，这些异构体消除了HF，得到环氧化物C_（60）F_（34）O ; C_（60）F_（36）O氧化物显示为醚，C_（60）F_（36）exi的第四种异构体
2. Novel facile routes for synthesis and isolation of fluorofullerenes C_(60)F_(18) and C_(60)F_(20) based on commercially available fluorinating reagents [J] . Pavel A.Troshin, Alexey B.Kornev, Alexander S.Peregudov, Journal of Fluorine Chemistry . 2005,第11a12期

机译：基于市售的氟化试剂合成和分离氟富勒烯C_（60）F_（18）和C_（60）F_（20）的新型简便路线
3. Core Electron Level Structure in C_(60)F_(18) and C_(60)F_(36) Fluorinated Fullerenes [J] . V. M. Mikoushkin, V. V. Shnitov, V. V. Bryzgalov, Technical physics letters: Letters to the Russian journal of applied physics . 2009,第3期

机译：C_（60）F_（18）和C_（60）F_（36）氟化富勒烯中的核心电子能级结构
4. ELECTRON TRANSFER REDUCTION OF FLUOROFULLERENES,C_(60)F_(36),AND C_(60)F_(18) [C] . Kei Ohkubo, Roger Taylor, Olga V.Boltalina, The Meeting of the Electrochemical Society . 2003

机译：电子转移氟化物，C_（60）F_（36），C_（60）F_（18）
5. Electronic structure of carbon(60), carbon(60) complexes, and actinocenes. [D] . Chang, Agnes Hsiu-Hwa. 1991

机译：碳（60），碳（60）配合物和放线菌的电子结构。
6. Electrochemical reduction of cationic Li+@C60 to neutral Li+@C60˙–: isolation and characterisation of endohedral 60fulleride [O] . Hiroshi Ueno, Shinobu Aoyagi, Yu Yamazaki, 2016

机译：电化学将阳离子Li + @ C60还原为中性Li + @ C60˙–：内面60富勒利德的分离和表征
7. ab initio modeling of open systems: charge transfer, electron conduction, and molecular switching of a C_{60} device [O] . Taylor, Jeremy, Guo, Hong, Wang, Jian 2000

机译：开放系统的ab initio建模：电荷转移，电子传导和C_ {60}器件的分子转换

Electron Transfer Reduction of Fluorofullerenes, C_(60)F_(18) and C_3 C_(60)F_(36)

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