CHEMICAL REDUCTION OF FULLERENES C_(60) AND C_(70) EMBEDDED IN CAST FILMS OF CATIONIC LIPIDS

机译：阳离子脂质铸膜中富勒烯C_（60）和C_（70）的化学还原

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Chemical generation of fullerene radical anions, C_(60)~(·-) and C_(70)~(·-) using a reducing reagent, Na_2S_2O_4, at thin films of lipids (amphiphiles) containing C_(60) or C_(70) were investigated. Visible-near IR spectra revealed that C_(60)~(·-) and C_(70)~(·-) were chemically produced at cationic lipid matrix films in aqueous media. The absorption maxima appeared at 1076-1078 nm and 1376-1378 nm for C_(60)~(·-) and C_(70)~(·-), respectively. On the contrary, C_(60)~(·-) and C_(70)~(?-) were not detected when neutral and anionic lipids were used instead of the cationic lipids. The chemical reduction for films of a single component of C_(60) and of C_(70) with Na_2S_2O_4 was also unable to detect. All results suggest that the charge of the matrix lipids and the formed microenvironments in the lipid films play important role for the generation of C_(60)~(·-) and C_(70)~(·-) at film states in aqueous media.

机译：使用还原剂Na_2S_2O_4在含有C_（60）或C_（70）的脂质（两亲物）薄膜上化学生成富勒烯自由基阴离子C_（60）〜（·-）和C_（70）〜（·-））进行了调查。可见-近红外光谱表明，C_（60）〜（·-）和C_（70）〜（·-）是在水性介质中的阳离子脂质基质薄膜上化学生成的。 C_（60）〜（·-）和C_（70）〜（·-）的最大吸收出现在1076-1078 nm和1376-1378 nm。相反，当使用中性和阴离子脂质代替阳离子脂质时，未检测到C_（60）-（·-）和C_（70）-（α--）。用Na_2S_2O_4也无法检测到C_（60）和C_（70）单一成分的薄膜的化学还原。所有结果表明，脂膜中基质脂质的电荷和形成的微环境对于水性介质中膜状态下C_（60）〜（·-）和C_（70）〜（·-）的生成起重要作用。。

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来源
《Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices: Fullorenes》|2003年|P.13-19|共7页
会议地点 Paris(FR);Paris(FR);Paris(FR)
作者
Takashi Nakanishi; Hiroto Murakami; Naotoshi Nakashima;
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Department of Materials Science, Graduate School of Science and Technology Nagasaki University, 1-14 Bunkyo, Nagasaki 852-8521, Japan;

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正文语种 eng
中图分类无机高分子化合物（高聚物）;
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1. EPR studies of the excited triplet states of C_(60)O and C_(60)C_2H_4N(CH_3) fullerene derivatives and C_(70) in toluene and polymethylmethacrylate glasses and as films [J] . G. Agostini, C. Corvaja, L. Pasimeni Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature . 1996,第2a3期

机译：EPR研究甲苯和聚甲基丙烯酸甲酯玻璃和薄膜中C_（60）O和C_（60）C_2H_4N（CH_3）富勒烯衍生物和C_（70）的激发三重态
2. The electrochemical reduction of fullerenes, C_(60) and C_(70) [J] . Guowang Diao, Liang Li, Zuxun Zhang Talanta: The International Journal of Pure and Applied Analytical Chemistry . 1996,第10期

机译：富勒烯C_（60）和C_（70）的电化学还原
3. Singly-bonded fullerene dimers: neutral (C_(60)Cl_5)_2 and cationic (C_(70))_2~(2+) [J] . Sergey I. Troyanov, Erhard Kemnitz Chemical Communications . 2007,第26期

机译：单键富勒烯二聚体：中性（C_（60）Cl_5）_2和阳离子（C_（70））_ 2〜（2+）
4. CHEMICAL REDUCTION OF FULLERENES C_(60) AND C_(70) EMBEDDED IN CAST FILMS OF CATIONIC LIPIDS [C] . Takashi Nakanishi, Hiroto Murakami, Naotoshi Nakashima International symposium on fullerenes, nanotubes, and carbon nanoclusters . 2003

机译：富勒烯C_（60）和C_（70）的化学还原在阳离子脂质的铸造膜中
5. The specific heat of C(70) fullerene, nanotubes, photo-polymerized C(60) fullerene, potassium doped fullerenes, and rubidium doped fullerenes. [D] . Budraa, Nasser Khalifa. 1996

机译：C（70）富勒烯，纳米管，光聚合的C（60）富勒烯，钾掺杂的富勒烯和rub掺杂的富勒烯的比热。
6. A retro Baeyer–Villiger reaction: electrochemical reduction of 60fullerene-fused lactones to 60fullerene-fused ketones [O] . Chuang Niu, Dian-Bing Zhou, Yong Yang, 2019

机译：Baeyer-Villiger逆反应：将60富勒烯融合的内酯电化学还原为60富勒烯融合的酮
7. Electrochemical and Chemical Reduction of Fullerenes C60 and C70 Embedded in Cast Films of Artificial Lipids in Aqueous Media [O] . -1

机译：富勒烯C60和C70的电化学和化学还原在水性介质中人工脂质的铸造膜中嵌入
8. Theoretical and experimental investigations of fullerene derivatives: C60H2, C60H4, C 70H2 and C60(CH2)2 [R] . Jacobs, S J, Gillen, K T, Cahill, P A, 1993

机译：富勒烯衍生物的理论和实验研究：C60H2，C60H4，C70H2和C60（CH2）2

CHEMICAL REDUCTION OF FULLERENES C_(60) AND C_(70) EMBEDDED IN CAST FILMS OF CATIONIC LIPIDS

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