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Physicochemical characterization of polymer composite cement systems

机译:聚合物复合水泥体系的理化特性

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摘要

The early hydration behaviour of two different polymer composites cement systems (PCCS) that hypothetically affects efflorescence has been investigated through physicochemical characterization namely Puddle Test (PT), Standard Chemical Method (SCM), Compressive Strength Test (CS), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). PCCS mortar samples were prepared with water-to-cement ratio (w/c) of 0.50. Commercially available polymer additives namely Styrene Butadiene Rubber (SBR) and Styrene Acrylic Ester (SAE) with different percentages of addition of 5%, 7% and 10% to cement were used. All samples were dried cured and tested at day 28. Efflorescence was accelerated by using PT. Its intensity, in terms of the amount of Calcium Carbonate (CaCO_3) precipitated on samples' surfaces, was quantified by using SEM. Results of the PCCS were then compared to the conventional cement system. Based on this study, PCCS can potentially reduce efflorescence where validation from CS, XRD analysis and SEM images showed that the evidence of the pore blocking effects of PCCS in early hydration hence can indirectly improve concrete durability and sustainability.
机译:已通过理化特性研究了两种可能假想影响风化的聚合物复合水泥系统(PCCS)的早期水化行为,即水坑试验(PT),标准化学方法(SCM),抗压强度试验(CS),X射线衍射( XRD)和扫描电子显微镜(SEM)。制备的PCCS砂浆样品的水灰比(w / c)为0.50。使用可商购获得的聚合物添加剂,即苯乙烯丁二烯橡胶(SBR)和苯乙烯丙烯酸酯(SAE),并向水泥中添加不同百分比的5%,7%和10%。将所有样品干燥固化并在第28天进行测试。通过使用PT促进了开花。通过使用SEM量化其强度,以沉淀在样品表面上的碳酸钙(CaCO_3)的量表示。然后将PCCS的结果与常规水泥系统进行比较。根据这项研究,PCCS可以潜在地减少风化,通过CS,XRD分析和SEM图像的验证表明,早期水化过程中PCCS的孔堵塞作用的证据因此可以间接改善混凝土的耐久性和可持续性。

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  • 来源
  • 会议地点 Ostend(BE)
  • 作者单位

    Department of Civil Engineering, Department of Chemical Engineering and Sustainability and Department of Mechanical Engineering, Faculty of Engineering, Univerisiti Malaysia Sarawak, Malaysia;

    Department of Civil Engineering, Department of Chemical Engineering and Sustainability and Department of Mechanical Engineering, Faculty of Engineering, Univerisiti Malaysia Sarawak, Malaysia;

    Department of Civil Engineering, Department of Chemical Engineering and Sustainability and Department of Mechanical Engineering, Faculty of Engineering, Univerisiti Malaysia Sarawak, Malaysia;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    polymer modified mortar; efflorescence; XRD; SEM;

    机译:聚合物改性砂浆;风化; XRD;扫描电镜;

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