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Conductivity and selectivity of ion exchange membranes: structure-correlations

机译:离子交换膜的电导率和选择性:结构相关性

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摘要

Apart from their stability in various operating conditions, the two main properties of ion-exchange membranes (IEMs) are the conductivity and selectivity, but both are difficult to obtain simultaneously at high values. This presentation deals with different ways of measurements, including specific characterization such as electrochemical impedance spectroscopy, Raman vibrational spectroscopy and radiotracers. Different transport models to reach fundamental transport parameters are also presented. Two cases of structure correlations will illustrate this topic: a cation-exchange membrane in strong basic solutions and a high-proton-conducting membrane based on sulfonated polyimide polymers.
机译:除了在各种操作条件下的稳定性外,离子交换膜(IEM)的两个主要特性是电导率和选择性,但是很难同时获得高值的离子交换膜。本演讲介绍了不同的测量方法,包括电化学阻抗光谱,拉曼振动光谱和放射性示踪剂等特定表征。还介绍了达到基本运输参数的不同运输模型。结构关联的两种情况将说明这一主题:在强碱性溶液中的阳离子交换膜和基于磺化聚酰亚胺聚合物的高质子传导膜。

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