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Conductivity and selectivity of ion exchange membranes: structure-correlations

机译:离子交换膜的电导率和选择性:结构相关性

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Apart from their stability in various operating conditions, the two main properties of ion-exchange membranes (IEMs) are the conductivity and selectivity, but both are difficult to obtain simultaneously at high values. This presentation deals with different ways of measurements, including specific characterization such as electrochemical impedance spectroscopy, Raman vibrational spectroscopy and radiotracers. Different transport models to reach fundamental transport parameters are also presented. Two cases of structure correlations will illustrate this topic: a cation-exchange membrane in strong basic solutions and a high-proton-conducting membrane based on sulfonated polyimide polymers.
机译:除了在各种操作条件下的稳定性外,离子交换膜(IEM)的两个主要性质是导电性和选择性,但两者难以在高值时同时获得。该介绍以不同的测量方式涉及不同的测量方法,包括特定表征,例如电化学阻抗光谱,拉曼振动光谱和放射性机构。还提出了不同的运输模型来达到基础传输参数。两种结构相关性将说明该主题:基于磺化聚酰亚胺聚合物的强碱性溶液中的阳离子交换膜和高质子导电膜。

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